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Nucleophilic Allylation of Acylsilanes in Water: An Effective Alternative to Functionalized Tertiary α-Silylalcohols.
Liang, Xiu-Xia; Zhu, Chen; Zhang, Wang; Du, Ya-Nan; Xu, Lei; Liu, Lihua; Zhang, Yicheng; Han, Man-Yi.
Afiliação
  • Liang XX; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Zhu C; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Zhang W; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Du YN; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Xu L; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Liu L; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Zhang Y; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
  • Han MY; Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
J Org Chem ; 88(16): 12087-12099, 2023 Aug 18.
Article em En | MEDLINE | ID: mdl-37497648
ABSTRACT
A nucleophilic allylation of acylsilanes in water was developed, generating versatile functionalized tertiary α-silyl alcohols in high yields. With the assistance of hydrogen bonding, a reaction model of less reactive acylsilane was achieved. Unlike the conventional strategy, transition metals and an additional Lewis acid catalyst were not required, and rate acceleration was observed in water.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2023 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2023 Tipo de documento: Article