Visible-light induced C(sp<sup>3</sup>)-H arylation of glycine derivatives by cerium catalysis.

Wang, Shutao; Ye, Yanjie; Shen, Hailong; Liu, Jiyu; Liu, Zhao; Jiang, Zhigen; Lei, Junqiang; Zhang, Yuan

Visible-light induced C(sp³)-H arylation of glycine derivatives by cerium catalysis.

Wang, Shutao; Ye, Yanjie; Shen, Hailong; Liu, Jiyu; Liu, Zhao; Jiang, Zhigen; Lei, Junqiang; Zhang, Yuan.

Afiliação

Wang S; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
Ye Y; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
Shen H; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
Liu J; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
Liu Z; First Hospital of Lanzhou University, Lanzhou 730000, P. R. China.
Jiang Z; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
Lei J; First Hospital of Lanzhou University, Lanzhou 730000, P. R. China.
Zhang Y; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.

Org Biomol Chem ; 21(41): 8364-8371, 2023 Oct 25.

Article em En | MEDLINE | ID: mdl-37815482

ABSTRACT

ABSTRACT

A Ce(III)-catalyzed, visible-light induced aerobic oxidative dehydrogenative coupling reaction between glycine derivatives and electron-rich arenes is disclosed. The protocol proceeds efficiently under mild conditions, providing an efficient method for the rapid synthesis of α-arylglycine derivatives without the need for an external photosensitizer and additional oxidant. Moreover, this protocol could be performed on a 5 mmol scale, without obvious reduction of the efficiency.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2023 Tipo de documento: Article

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