A case of alkylidyne-imine metathesis.

Yadav, Rinku; Ghiviriga, Ion; Abboud, Khalil K; Veige, Adam S

Yadav, Rinku; Ghiviriga, Ion; Abboud, Khalil K; Veige, Adam S.

Afiliação

Yadav R; Department of Chemistry, Center for Catalysis, University of Florida, Gainesville, Florida, 32611, USA. veige@chem.ufl.edu.
Ghiviriga I; Department of Chemistry, Center for Catalysis, University of Florida, Gainesville, Florida, 32611, USA. veige@chem.ufl.edu.
Abboud KK; Department of Chemistry, Center for Catalysis, University of Florida, Gainesville, Florida, 32611, USA. veige@chem.ufl.edu.
Veige AS; Department of Chemistry, Center for Catalysis, University of Florida, Gainesville, Florida, 32611, USA. veige@chem.ufl.edu.

Chem Commun (Camb) ; 59(86): 12899-12902, 2023 Oct 26.

Article em En | MEDLINE | ID: mdl-37819671

ABSTRACT

ABSTRACT

Reactions between imines and tungsten alkylidyne complexes are studied. The trianionic pincer ligand supported alkylidyne [tBuOCO]WCC(CH3)3(THF)2 (1) reacts with N-(R)-1-phenylmethanimine (PMI-R, R = Me, Ph, Bn, and TMS) yielding [tBuOC(H)O]W(Î·2-tBuCîCPh)N(R) (4-R), products from metathesis reaction. In contrast, the non-pincer alkylidyne (tBuO)3WîCC(CH3)3 does not react with PMI-R imines.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Estados Unidos

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