Revealing the intrinsic nature of Ni-, Mn-, and Y-doped CeO2 catalysts with positive, additive, and negative effects on CO oxidation using operando DRIFTS-MS.
Dalton Trans
; 52(45): 16911-16919, 2023 Nov 21.
Article
em En
| MEDLINE
| ID: mdl-37927054
ABSTRACT
The catalytic activity of a transition metal (host) oxide can be influenced by doping with a second cation (dopant), but the key factors dominating the activity of the doped catalyst are still controversial. Herein, CeO2 doped with Ni, Mn, and Y catalysts prepared using aerosol pyrolysis were used to demonstrate the positive, negative, and additive effects on CO oxidation as a model reaction. Various characterization results indicated that Ni, Mn, and Y had been successfully doped into the CeO2 lattice. The catalytic activities of each catalyst for CO conversion were in the order of Ni-CeO2 > Mn-CeO2 > CeO2 > Y-CeO2. Operando DRIFTS-MS and various characterization methods were applied to reveal the intrinsic nature of the doping effects. The accumulation rate of the surface bidentate carbonates determined the CO oxidation. A definition to evaluate the doping effect was proposed, which is anticipated to be useful for developing a rational catalyst with a high CO oxidation activity. The CO oxidation reactivities displayed strong correlations with the surface factors obtained from operando DRIFTS-MS analysis and the structure factors from XPS and Raman analyses.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
China