Low-valent-tungsten catalysis enables hydroboration of esters and nitriles.

Song, Heng; Xiao, Yuting; Wei, Jingjing; Liu, Yuzan; Yang, Liqing; Bai, Pengtao; Yang, Fu; Yu, Kai; Xu, Chen; Cai, Xingwei

Song, Heng; Xiao, Yuting; Wei, Jingjing; Liu, Yuzan; Yang, Liqing; Bai, Pengtao; Yang, Fu; Yu, Kai; Xu, Chen; Cai, Xingwei.

Afiliação

Song H; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Xiao Y; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Wei J; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Liu Y; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Yang L; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Bai P; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Yang F; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Yu K; School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, P. R. China.
Xu C; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.
Cai X; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, Jiangsu, P. R. China. hengsong@just.edu.cn.

Chem Commun (Camb) ; 60(38): 5026-5029, 2024 May 07.

Article em En | MEDLINE | ID: mdl-38629636

ABSTRACT

ABSTRACT

In the research presented herein, low-valent-tungsten-catalyzed hydroboration of esters and nitriles was investigated. Aromatic and aliphatic substrates were smoothly reduced to corresponding alcohol derivatives and N,N-diborylamines in the presence of W(CO)4(NCMe)2. Valuable derivatives were conveniently accessed by introducing a further functionalization process to crude hydroboration mixtures in one pot.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article

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