Pyridinethiolate-Capped CdSe Quantum Dots for Red-Light-Driven H2 Production in Water.
Chemistry
; 30(47): e202401475, 2024 Aug 22.
Article
em En
| MEDLINE
| ID: mdl-38888382
ABSTRACT
The utilization of low-energy sunlight to produce renewable fuels is a subject of great interest. Here we report the first example of metal chalcogenide quantum dots (QDs) capped with a pyridinethiolate carboxylic acid (pyS-COOH) for red-light-driven H2 production in water. The precious-metal-free system is robust over 240â
h, and achieves a turnover number (TON) of 43910±305 (vs Ni) with a rate of 31570±1690â
µmol g-1 h-1 for hydrogen production. In contrast to the inactive QDs capped with other thiolate ligands, the CdSe-pyS-COOH QDs give a significantly higher singlet oxygen quantum yield [ΦΔ (1O2)] in solution.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemistry
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China