Nanoparticle Superlattices Driven by Linker-Mediated Covalent Bonding Interaction.
J Phys Chem Lett
; 15(25): 6691-6698, 2024 Jun 27.
Article
em En
| MEDLINE
| ID: mdl-38899919
ABSTRACT
The stability of the nanoparticle superlattice (NPSL) is essential for realizing its broad spectrum of potential applications. Here, we report a linker-mediated covalent bonding interaction method for the synthesis of highly stable NPSLs. Adipic acid is used as a linker molecule which connects two Au NPs functionalized with 6-mercaptohexanol through esterification reactions in the presence of H2SO4. As-prepared NPSLs are mostly fcc Wulff polyhedra with a fairly narrow size distribution and are highly stable in solvents of different polarities and pHs (0-14) as well as in dry conditions and at temperatures as high as 175 °C. The formation of NPSLs involves random homogeneous nucleation simultaneously accompanied by growth, a gradual change of the growth mode from reaction-controlled to diffusion-controlled with time, and the oriented attachments of small crystals. The size of the NPSL can be easily tuned by the concentration of linker molecules and the reaction temperature.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Phys Chem Lett
Ano de publicação:
2024
Tipo de documento:
Article