[Bi10{RuPPh3}3]-: Paramagnetic 13-Vertex Polybismuthide Heteroanion.

Wang, Yueyue; Li, Yankai; Sang, Ruili; Xu, Li

[Bi₁₀{RuPPh₃}₃]^-: Paramagnetic 13-Vertex Polybismuthide Heteroanion.

Wang, Yueyue; Li, Yankai; Sang, Ruili; Xu, Li.

Afiliação

Wang Y; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Li Y; University of the Chinese Academy of Sciences, Beijing 100049, China.
Sang R; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Xu L; College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, China.

Inorg Chem ; 2024 Jul 16.

Article em En | MEDLINE | ID: mdl-39012053

ABSTRACT

ABSTRACT

Ru(PPh3)3Cl2 reacts with Binn- from an ethylenediamine (en) solution of K5Bi4 to yield a new architype of 13-vertex [Bi10{RuPPh3}3]- (1) composed of unprecedented incomplete cuboidal Bi73- and triangular Bi33- held together by {RuPPh3}2+.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China

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