Effect of microplastics on urban wastewater disinfection and impact on effluent reuse: Sunlight/H2O2 vs solar photo-Fenton at neutral pH.

The interference of three types of microplastics (MPs) on the inactivation of Escherichia coli (E. coli) by advanced oxidation processes (AOPs) (namely, sunlight/H2O2 and solar photo-Fenton (SPF) with Ethylenediamine-N,N'-disuccinic acid (EDDS)), in real secondary treated urban wastewater was investigated for the first time. Inactivation by sunlight/H2O2 treatment decreased as MPs concentration and H2O2 dose were increased. Noteworthy, an opposite behaviour was observed for SPF process where inactivation increased as MPs concentration was increased. Biofilm formation and microbial attachment on surfaces of post-treated MPs were observed on polyethylene (PE) and polyvinyl chloride (PVC) MPs by field emission scanning electron microscopy. In presence of PE MPs, a complete inactivation of E. Coli was achieved by SPF with EDDS (Fe:EDDS = 1:2) after 90 min treatment unlike of sunlight/H2O2 treatment (∼4.0 log reduction, 40 mg/L H2O2 dose, 90 min treatment). The lower efficiency of sunlight/H2O2 process could be attributed to the blocking/scattering effect of MPs on sunlight, which finally reduced the intracellular photo Fenton effect. A reduced E. coli regrowth was observed in presence of MPs. SPF (Fe:EDDS = 1:1) with PE MPs was less effective in controlling bacterial regrowth (∼120 CFU/100 mL) than sunlight/H2O2 (∼10 CFU/100 mL) after 48 h of post-treatment. These results provide useful information about possible interference of MPs on urban wastewater disinfection by solar driven AOPs and possible implications for effluent reuse.

Urban wastewater disinfection by FeCl3-activated biochar/peroxymonosulfate system: Escherichia coli inactivation and microplastics interference.

Biochar coupled with peroxymonosulfate (PMS) to produce sulfate radicals and its application to urban wastewater disinfection has been rarely investigated and no information is available about microplastics (MPs) interference on the disinfection process. In this study, FeCl3-activated biochar (Fe-BC) was coupled to PMS to evaluate the inactivation of Escherichia coli (E. coli) in real secondary treated urban wastewater. Surface morphology of Fe-BC sample, characterized by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS), showed a rough texture with uniform distribution of iron particles over the entire surface area. E. coli inactivation improved (∼3.8 log units, detection limit = 1 CFU/100 mL) as Fe-BC concentration was decreased (from 1.0 g/L to 0.5 g/L), at a constant PMS dose (300 mg/L). Besides, removal efficiency of E. coli was negatively affected by the presence of small (30-50 µm) polyethylene MPs (PE MPs) (200 mg/L), which could be attributed to the adsorption of MPs on Fe-BC surface, according to SEM images of post-treated Fe-BC. The low disinfection efficiency of Fe-BC/PMS system in presence MPs could be due to blocking of Fe-BC sites for PMS activation and/or radicals scavenging during treatment. These results allowed to unveil the mechanisms of MPs interference on E. coli inactivation by Fe-BC/PMS, as well as the potential of this process to make the effluent in compliance with the stringent limit for agricultural reuse.

Phenol separation from phenol-laden saline wastewater by membrane aromatic recovery system-like membrane contactor using superhydrophobic/organophilic electrospun PDMS/PMMA membrane.

Phenol recovery from phenol-laden saline wastewater plays an important role in the waste reclamation and pollution control. A membrane aromatic recovery system-like membrane contactor (MARS-like membrane contactor) was set up in this study using electrospun polydimethylsiloxane/polymethyl methacrylate (PDMS/PMMA) membrane with 0.0048 m2 effective area to separate phenol from saline wastewater. Phenol and water contact angles of 0° and 162° were achieved on this membrane surface simultaneously, indicating its potential in the separation of phenol and water-soluble salt. Feed solution (500 mL) of 0.90 L/h and receiving solution (500 mL) of 1.26 L/h were investigated to be the optimum conditions for phenol separation, which corresponds to the employed Reynolds number of 14.6 and 20.5. During 108-h continuous separation for feed solution (2.0 g/L phenol, 10.0 g/L NaCl) under room temperature (20 °C), 42.6% of phenol was recycled in receiving solution with a salt rejection of 99.95%. Meanwhile, the mean phenol mass transfer coefficient (Kov) was 6.7 × 10-7 m s-1. As a membrane-based process, though the permeated phenol increased with the increase of phenol concentration in feed solution, the phenol recovery ratio was determined by the membrane properties rather than the pollutant concentrations. Phenol was found to permeate this membrane via adsorption, diffusion and desorption, and therefore, the membrane fouling generated from pore blockage in other membrane separation processes was totally avoided.