The interactions of Cr (VI) concentrations and amendments (biochar and manure) on growth and metal accumulation of two species of Salicornia in contaminated soil.

Heavy metals are among the most dangerous contaminants in the environment. Organic components and plant species that can accumulate and stabilize heavy metals in their organs are a good option for soil remediation of these elements. Therefore, this study aimed to investigate the effects of manure and biochar on the accumulation of heavy metals by Salicornia species. Salicornia persica Akhani and Salicornia perspolitana Akhani were cultivated outdoor in experimental pots. The effects of experimental treatments, including Cr (VI) concentrations, manure, and biochar on the two studied species, were investigated. The results indicated a significant effect (p < 0.05) of biochar on the accumulation of heavy metals by two species, S. persica and S. perspolitana, so that Cr concentrations in the roots and shoots were 258 and 5.41 mg/kg, respectively. In addition, Cr accumulations under manure treatments in the roots and shoots were 334.34 and 9.79 mg/kg, respectively. The content of photosynthetic pigments in both S. persica and S. perspolitana species under biochar treatment was higher than in control and manure treatments. In general, one can conclude that the accumulation of Cr in S. perspolitana was higher than in S. persica. Applying biochar and manure amendments could stabilize Cr in soil and reduce Cr accumulation in both S. persica and S. perspolitana species.

Application of response surface methodology for optimization of lead biosorption in an aqueous solution by Aspergillus niger.

Response surface methodology was applied to optimize the removal of lead ion by Aspergillus niger in an aqueous solution. Experiments were conducted based on a rotatable central composite design (CCD) and analyzed using response surface methodology (RSM). The biosorption process was investigated as a function of three independent factors viz. initial solution pH (2.8-7.2), initial lead concentration (8-30 mg/l) and biomass dosage (1.6-6 g/l). The optimum conditions for the lead biosorption were found to be 3.44, 19.28 mg/l and 3.74 g/l, respectively, for initial solution pH, initial lead ion concentration and biomass dosage. Lead biosorption capacity on dead A. niger fungal biomass was enhanced by pretreatment using NaOH. Under these conditions, maximum biosorption capacity of the biomass for removal of lead ions was obtained to 96.21%. The desirability function was used to evaluate all the factors and response in the biosorption experiments in order to find an optimum point where the desired conditions could be obtained. The A. niger particles with clean surface and high porosity may have application as biosorbent for heavy metal removal from wastewater effluents.

Determination of optimum conditions for dairy wastewater treatment in UAASB reactor for removal of nutrients.

In this study, the granular sludge was generated for simultaneous nitrification, denitrification and phosphorus removal (SNDPR) and studied on a laboratory scale. Analyzing the nutrients removal percentages from wastewater were scrutinized by using an optimization of the variables, i.e., COD:N:P ratio, OLR, aeration time, MLSS, F:M and HRT. These 6 interrelated parameters were evaluated as the process response. Microscopic observations of the performance of the SNDPR process revealed that the granules included Bacillus sp. in the bacterial community. According to these results, the UAASB system produced an effluent that lends dairy wastewater suitable for land irrigation and that this an attractive process of using granular sludge is appropriate for achieving carbon, nitrogen and phosphorus removal from nutrient-rich wastewater by a biological method.

Mercury concentration in the breast milk of Iranian women.

Human milk is usually the only source of food for infants during the first 4 to 5 months of their life. In this research, 80 human milk samples were collected from mothers in Tehran, Noushahr and the countryside of Tabriz, Iran, who were not occupationally exposed to mercury. The mean concentration of mercury in breast milk obtained from mothers in the countryside of Tabriz, Noushahr and Tehran was 0.86, 0.15 and 0.12 µg/L, respectively. There was a significant difference in mercury concentration in human breast milk between that from the countryside of Tabriz with that from Tehran and Noushahr. Only 3.7% of infant samples (three infants) had mercury concentration higher than normal versus the WHO recommended limit (0.5 µg g(-1)). The fish consumption of these mothers in Tehran and Noushahr was a factor that significantly affected the mercury concentration in their breast milk. Also, their age affected the mercury levels in breast milk (p = 0.04).

Biosorption of nickel(II) from aqueous solution by Aspergillus niger: response surface methodology and isotherm study.

In the present study, the effects of biosorbent Aspergillus niger dosage, initial solution pH and initial Ni(II) concentration on the uptake of Ni(II) by NaOH pretreated biomass of A. niger from aqueous solution were investigated. Batch experiments were carried out in order to model and optimize the biosorption process. The influence of three parameters on the uptake of Ni(II) was described using a response surface methodology (RSM) as well as Langmuir and Freundlich isotherm models. Optimum Ni(II) uptake of 4.82 mg Ni(II)g(-1) biomass (70.30%) was achieved at pH 6.25, biomass dosage of 2.98 gL(-1) and initial Ni(II) concentration of 30.00 mgL(-1) Ni(II). Langmuir and Freundlich were able to describe the biosorption isotherm fairly well. However, prediction of Ni(II) biosorption using Langmuir and Freundlich isotherms was relatively poor in comparison with RSM approaches. The biosorption mechanism was also investigated by using Fourier transfer infrared (FT-IR) analysis of untreated, NaOH pretreated, and Ni(II) loaded A. niger biomass.