RESUMEN
The heterostructure of transition-metal chalcogenides is a promising approach to boost alkali ion storage due to fast charge kinetics and reduction of activation energy. However, cycling performance is a paramount challenge that is suffering from poor reversibility. Herein, it is reported that Se-rich particles can chemically interact with local hexagonal ZnSe/MnSe@C heterostructure environment, leading to effective ions insertion/extraction, enabling high reversibility. Enlightened by theoretical understanding, Se-rich particles endow high intrinsic conductivities in term of low energy barriers (1.32 eV) compared with those without Se-rich particles (1.50 eV) toward the sodiation process. Moreover, p orbitals of Se-rich particles may actively participate and further increase the electronegativity that pushes the Mn d orbitals (dxy and dx2-y2) and donate their electrons to dxz and dyz orbitals, manifesting strong d-d orbitals interaction between ZnSe and MnSe. Such fundamental interaction will adopt a well-stable conducive electronic bridge, eventually, charges are easily transferred from ZnSe to MnSe in the heterostructure during sodiation/desodiation. Therefore, the optimized Se-rich ZnSe/MnSe@C electrode delivered high capacity of 576 mAh g-1 at 0.1 A g-1 after 100 cycles and 384 mAh g-1 at 1 A g-1 after 2500 cycles, respectively. In situ and ex situ measurements further indicate the integrity and reversibility of the electrode materials upon charging/discharging.
RESUMEN
The development of electrochemically inexpensive, durable, and active electrocatalysts for the oxygen evolution reaction (OER) is attracting considerable attention. The heterogeneous interfacing might regulate the electronic structure and further improve the electrochemical activity. Herein, a Ce(OH)3 nanoparticle-interfaced Fe-doped nickel sulfide (Ce(OH)3@Fe-Ni3S2) electrocatalyst was prepared to improve the OER performance. The fabricated electrocatalyst displayed excellent intrinsic activity and long-term stability in 1 M KOH for the OER. The catalyst shows an ultralow overpotential of 195 mV at a current density of 10 mA cm-2 and a Tafel slope of 52 mV dec-1, which are remarkably smaller than those of the control samples. This excellent electrocatalytic activity is attributed to the incorporation of Ce(OH)3 nanoparticles on the surface of the Fe-Ni3S2 nanosheet, which increases the electrochemical activity and enlarges the active surface area of the catalyst. In comparison to previous nonprecious OER electrocatalysts, the prepared Ce(OH)3@Fe-Ni3S2 exhibits greater electrocatalytic activity and longer durability, allowing for the selection of new electrocatalysts for practical applications.