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Bioresour Technol ; 132: 254-61, 2013 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-23411456

RESUMEN

Fibres from oil palm empty fruit bunches, generated in large quantities by palm oil mills, were processed into self-adhesive carbon grains (SACG). Untreated and KOH-treated SACG were converted without binder into green monolith prior to N2-carbonisation and CO2-activation to produce highly porous binderless carbon monolith electrodes for supercapacitor applications. Characterisation of the pore structure of the electrodes revealed a significant advantage from combining the chemical and physical activation processes. The electrochemical measurements of the supercapacitor cells fabricated using these electrodes, using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge-discharge techniques consistently found that approximately 3h of activation time, achieved via a multi-step heating profile, produced electrodes with a high surface area of 1704m(2)g(-1) and a total pore volume of 0.889cm(3)g(-1), corresponding to high values for the specific capacitance, specific energy and specific power of 150Fg(-1), 4.297Whkg(-1) and 173Wkg(-1), respectively.


Asunto(s)
Arecaceae/química , Carbono/química , Electroquímica/métodos , Electrodos , Frutas/química , Biomasa , Carbono/análisis , Dióxido de Carbono/química , Espectroscopía Dieléctrica , Nitrógeno/química , Factores de Tiempo
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