Synergistic Effect of Sr-O Divacancy and Exposing Facets in SrTiO3 Micro/Nano Particle: Accelerating Exciton Formation and Splitting, Highly Efficient Co2+ Photooxidation.

As a typical perovskite-type crystal, polyhedral strontium titanate (SrTiO3 ) has shown anisotropic charge transport behavior in recent studies, however, the carrier transportation and transition of which has not been explained very clearly. This work present the existence of Sr and O divacancies in the novel rhombicuboctahedron SrTiO3 micro/nano particles (Sr1- x TiO3- x /TiO2- x ) with exposing (100), (110) and (111) facets and the diameter of 300-700 nm synthesized via hydrothermal synthesis, and also summarizes the dissociation mechanism of self-trapped excitons (STEs) caused by the divacancy and facet effect. In addition, most importantly, the metastable STEs with ultra-low binding energy (Eb  < 3 meV) under illumination are discovered. Combining the model of S-scheme heterojunction, a conversion mechanism of photoinduced carriers is proposed. The photocatalytic reaction of Co2+ is used as the probe reaction, and the unique Sr1- x TiO3- x /TiO2- x possesses a high photooxidation efficiency of Co2+ , by which 70.3% of Co2+ is oxidized to Co3+ (CoOOH) in 5 min. This finding may provide a guideline for an optimal design of the photocatalytic materials for the recovery and extraction of metal ions based on SrTiO3 .

Layer-Controlled Synthesis of a Silanol-Graphene Oxide Nanosheet Composite Forward Osmosis Membrane by Surface Self-Assembly.

More and more two-dimensional materials, such as graphene, are used in water separation membrane synthesis. Among the main influencing factors, surface properties and the interface structure of multilayers are the two crucial factors to the membrane separation performance. In the present paper, a silanol ((SiO3)x) and graphene oxide nanosheet composite (GO-(SiO3)x) was used to synthesize a skin like forward osmosis (FO) membrane for desalination by a surface layer-by-layer self-assembly method. We tested the separation performance of the FO membranes using DI water and 1.5 M NaCl aqueous solutions as feed and draw solutions, respectively. The results show that the molecular size and particle morphology of (SiO3)x grafted onto GO nanosheets play main roles in the water flux of the composite membrane. Based on this property and the self-assembly method, we can control the number of composite layers and the space between the GO nanosheets. Simultaneously, we have introduced a new concept: dilutive "skin layer concentration polarization (SLCP)" and the concentrative external concentration polarization (ECP) effect at the membrane surface are considered. The FO membrane synthesized in the current study exhibits a high level of water flux (above 30 L·m-2·h-1), and the salt retention capacity of the membranes increases as the number of composite layers increases. Thus, in this article, we find a way to create suitable water channels for separation of salt/water in a FO process by controlling the GO-(SiO3)x content and size.

strong synergistic effect of the (110) and (100) facets of the SrTiO3 perovskite micro/nanocrystal: decreasing the binding energy of exciton and superb photooxidation capability for Co2.

Crystal facet regulation is an effective method for preparing SrTiO3 or other perovskite semiconductor materials with high photochemical catalysis performance. In general, the edge-truncated cube of SrTiO3 micro-nano particles has been widely reported because of the multiple crystal facets exposed at the same time. However, the effect of the (110) facet and the interaction between the (100) and (110) facets on the properties of photo-induced carriers is still not very clear. In this article, we have designed and prepared two edge-truncated cube SrTiO3-a small and large area proportion of the (110) facet, respectively. In addition to the morphological and structural characterization, high-resolution XPS and femtosecond multiphoton transient absorption (fs-TA) spectroscopy were used to detect the atomic vacancy and were applied to confirm the state of carrier transition. The results showed that the larger (110) facet led to two influences-more Sr vacancies and more self-trapping excitons (STEs) with an ultra-low binding energy (Eb = 2.13 meV), about 1.17 meV lower than that of the sample with the smaller (110) facet. In particular, the larger (110) facet also caused a much higher photooxidation performance for Co2+ to Co3+. This study not only enriches the arsenal of SrTiO3 materials but also sheds new insights into the understanding of the synergistic effect essence of the (100) and (110) facets, which could promote the development of new perovskite photocatalytic materials, particularly in the recovery of heavy metals.

Inorganic pollution around the Qinghai-Tibet Plateau: An overview of the current observations.

The Qinghai-Tibet Plateau is the highest geographical unit in the world. Thus, it serves an important role in evaluating long-term ecologic conditions and environmental status and changes over time. This study summarizes major and trace element concentrations in biota and in water and soil. It also pays attention to gaseous pollutant and particle concentrations in air around the Qinghai-Tibet Plateau. The degree of soil heavy metal contamination and the water heavy metal hazard index were respectively evaluated. The contamination degrees of two sampling areas around the Qinghai-Tibet Plateau reached extremely high levels with soil mCd (modified degree of contamination) values exceeding 20. Surprisingly, over 54% of sampling areas showed moderate or more serious soil contamination degree (mCd>1.5). Moreover, the hazard indexes of two important rivers were 1.56 and 7.59, reaching unacceptable level. The potential risk might be beyond our expectation. Therefore, it should be an urgent and top priority to identify and confirm possible pollution sources around the Qinghai-Tibet Plateau. Then, it is imperative to implement feasible and effective environmental quality control strategies.

Eco-Physiological Responses of Dominant Species to Watering in a Natural Grassland Community on the Semi-Arid Loess Plateau of China.

Altered precipitation regimes significantly affect ecosystem structure and function in arid and semi-arid regions. In order to investigate effects of precipitation changes on natural grassland community in the semi-arid Loess Plateau, the current research examined eco-physiological characteristics of two co-dominant species (i.e., Bothriochloa ischaemum and Lespedeza davurica) and community composition following two watering instances (i.e., precipitation pulses, July and August, 2011, respectively) in a natural grassland community. Results showed that the photosynthetic rate, transpiration rate, stomatal conductance and intercellular CO2 concentration rapidly increased on the first to third day following watering in both species, and both months. Under watering treatments, the maximum net photosynthetic rates appeared on the second to third day after watering, which increased 30-80% in B. ischaemum and 40-50% in L. davurica compared with non-watering treatments, respectively. Leaf water use efficiency kept stable or initially decreased in both species under watering treatments. Watering in July produced more promoting effects on grass photosynthesis than in August, particularly in B. ischaemum. Community above-ground biomass at the end of the growing season increased after watering, although no significant changes in species diversity were observed. Our results indicated that timing and magnitude of watering could significantly affect plant eco-physiological processes, and there were species-specific responses in B. ischaemum and L. davurica. Pulsed watering increased community productivity, while did not significantly alter community composition after one growing season. The outcomes of this study highlight eco-physiological traits in dominant species may playing important roles in reshaping community composition under altered precipitation regimes.

An overview on the organic pollution around the Qinghai-Tibet plateau: The thought-provoking situation.

The Qinghai-Tibet Plateau plays an important role in the ecological safety and human health of the surroundings due to its unique geographical position and function. Therefore, it is necessary to study the pollution status and potential risk in this area. This study summarizes the distribution of different organic pollutants in biota and environmental media of the Qinghai-Tibet Plateau. Moreover, it also pays attention to the potential health risks of these organic pollutants. Organochlorine pesticides (OCPs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) were the most frequently detected in different matrices. In general, the carcinogenic risks of organic pollutants were ranked in the very-low to moderate range for both children and adults. The carcinogenic risks of organic pollutants in fish, food, and water for children were 1-2 times higher than those for adults, while risks of organic pollutants in soil/sediment and in air for children were generally 10.6-16.5 and 2.6-2.8 times higher than those for adults, respectively. The maximal hazard quotient for non-carcinogenic risk was 0.95 (potential risk for children posed by organic pollutants in yak milk of Ruoergai), almost reaching an unacceptable level. Therefore, the potential health risks could not be neglected, especially for children who were more likely to be affected by the pollutants.