1.
Org Biomol Chem
; 9(13): 4778-81, 2011 Jul 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21629924
RESUMEN
Under catalysis with ZnI(2), an effective annulation process of ω-silylacetylenic α-cyano ketones, leading to the formation of various bicyclic frameworks characterized with a TMS-containing methylenecyclopentane ring, has been developed.
Asunto(s)
Alcanos/síntesis química , Alquinos/química , Cianuros/química , Compuestos de Trimetilsililo/química , Ciclización , Cetonas , Estructura Molecular
2.
Org Biomol Chem
; 7(16): 3285-90, 2009 Aug 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-19641787
RESUMEN
Starting from 4-methylcyclohexanone (7), a concise total synthesis of the pinguisane-type sesquiterpenoid acutifolone A, in racemic form, has been accomplished in 14 steps with an overall yield of 14.5%.