Polymer Photocatalysts Containing Segregated π-Conjugation Units with Electron-Trap Activity for Efficient Natural-light-driven Bacterial Inactivation.

Development of highly efficient and metal-free photocatalysts for bacterial inactivation under natural light is a major challenge in photocatalytic antibiosis. Herein, we developed an acidizing solvent-thermal approach for inserting a non-conjugated ethylenediamine segment into the conjugated planes of 3,4,9,10-perylene tetracarboxylic anhydride to generate a photocatalyst containing segregated π-conjugation units (EDA-PTCDA). Under natural light, EDA-PTCDA achieved 99.9 % inactivation of Escherichia coli and Staphylococcus aureus (60 and 45 min), which is the highest efficiency among all the natural light antibacterial reports. The difference in the surface potential and excited charge density corroborated the possibility of a built-in electron-trap effect of the non-conjugated segments of EDA-PTCDA, thus forming a highly active EDA-PTDA/bacteria interface. In addition, EDA-PTCDA exhibited negligible toxicity and damage to normal tissue cells. This catalyst provides a new opportunity for photocatalytic antibiosis under natural light conditions.

Indium doped bismuth subcarbonate nanosheets for efficient electrochemical reduction of carbon dioxide to formate in a wide potential window.

Electrochemical carbon dioxide (CO2) reduction reaction (E-CO2RR) to formate with high selectivity driven by renewable electricity is one of the most promising routes to carbon neutrality. Herein, we developed a novel indium (In)-doped bismuth subcarbonate (BOC) nanosheets (BOC-In-x NSs) through transformation of In-doped bismuth (Bi) nanoblocks (Bi-In-x NBs). The BOC-In-0.1 NSs achieved a maximum Faraday efficiency of formate (FEformate) nearly 100% with high stability (22 h) and an appreciable average FEformate of 93.5% in a wide potential window of 450 mV. The experimental and theoretical calculations indicate that the incorporation of In into BOC nanosheets enhanced the adsorption of CO2 and the intermediates during the process of E-CO2RR, and reduced the energy barrier for the formation of formate.