1.
Angew Chem Int Ed Engl
; 58(7): 2120-2124, 2019 Feb 11.
Artículo
en Inglés
| MEDLINE
| ID: mdl-30561885
RESUMEN
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.