RESUMEN
Most rubber products come from petrochemical resources, which are increasingly in short supply. Rubber products that formed irreversible chemical bonds in the vulcanization process are difficult to recycle, resulting in a serious waste of resources. Therefore, it is important to prepare a kind of reprocessable biobased elastomers. Using furfuryl methacrylate (FMA) as the modified monomer, poly(dibutyl itaconate-myrcene-furfuryl methacrylate) (PDBIMFA) was synthesized by high-temperature emulsion polymerization successfully. The structure and compositions of PDBIMFA were characterized by Fourier transform infrared and 1H NMR, and the effects of different FMA contents on the structures and properties of PDBIMFA were systematically studied. Based on the Diels-Alder reaction, bismaleimide (BMI) and carbon black (CB) were introduced into PDBIMFA as cross-linking agents and reinforcing fillers, respectively, by the melt blending method, and PDBIMFA-BMI elastomer materials and CB/PDBIMFA-BMI elastomer composites with thermo-reversible cross-linking characteristics were prepared. The effects of the ratio of FMA and BMI on the mechanical properties of PDBIMFA-BMI were studied. PDBIMFA-BMI and CB/PDBIMFA-BMI were reprocessed twice, and the recovery rate of tensile strength was both more than 90%. The addition of CB was found to play a reinforcing role in the elastomer and with the introduction of the amount of CB, the reprocessability of composite remained at a good level. It is hoped that this research will provide a new strategy for the sustainable development of bio-based elastomer materials.
RESUMEN
Reverse atom transfer radical polymerization (RATRP) was used to synthesize poly(dimethyl itaconate) (PDMI) using an AIBME/CuBr2/dNbpy system. The number average molecular weight (M n) of PDMI was as high as M n = 15 000 g mol-1, the monomer conversion rate reached up to 70%, and the dispersity remained low (D = 1.06-1.38). The first-order kinetics of PDMI are discussed in detail. The AIBME initiator had a higher initiation efficiency than the AIBN initiator. As the ratio of initiator (AIBME) to catalyst (CuBr2) decreased, the M n and D of PDMI decreased. At 60 °C and 80 °C, the M n of PDMI was much higher than the theoretical number average (M n,th), and the D of PDMI broadened with the conversion rate. At 100 °C, the D of PDMI remained low, and the M n of PDMI was closer to the M n,th. As the ratio of monomer (DMI) to initiator (AIBME) increased, the M n of PDMI changed little over time. These phenomena could be explained by the influence of the initiator and catalyst on polymerization kinetics.
RESUMEN
A novel elastomer poly(diethyl itaconate-co-butyl acrylate-co-ethyl acrylate-co-glycidyl methacrylate) (PDEBEG) was designed and synthesized by redox emulsion polymerization based on bio-based diethyl itaconate, butyl acrylate, ethyl acrylate, and glycidyl methacrylate. The PDEBEG has a number average molecular weight of more than 200,000 and the yield is up to 96%. It is easy to control the glass transition temperature of the PDEBEG, which is ranged from -25.2 to -0.8 °C, by adjusting the monomer ratio. We prepared PDEBEG/CB composites by mixing PDEBEG with carbon black N330 and studied the oil resistance of the composites. The results show that the tensile strength and the elongation at break of the composites with 10 wt% diethyl itaconate can reach up to 14.5 MPa and 305%, respectively. The mechanical properties and high-temperature oil resistance of the composites are superior to that of the commercially available acrylate rubber AR72LS.
RESUMEN
Ester-functionalized styrene-butadiene rubber (dibutyl itaconate-styrene-butadiene rubber) (D-ESBR) was synthesized by low-temperature emulsion polymerization using dibutyl itaconate (DBI) as a modified monomer containing ester groups. Nonpetroleum-based silica with hydroxy groups was used as a filler to enhance the D-ESBR, which can provide excellent mechanical properties, low rolling resistance, and high wet skid resistance. During the preparation of the silica/D-ESBR nanocomposites, a hydrogen-bonding interface was formed between the hydroxy groups on the surface of silica and the ester groups in the D-ESBR macromolecules. As the content of ester groups in the D-ESBR increases, the dispersion of silica in the nanocomposites is gradually improved, which was verified by rubber process analyzer (RPA) and scanning electron microscopy (SEM). Overall mechanical properties of the silica/D-ESBR modified with 5 wt % DBI were improved and became superior to that of the non-modified nanocomposite. Compared with the non-modified silica/D-ESBR, the DBI modified silica/D-ESBR exhibited a lower tan δ value at 60 °C and comparable tan δ value at 0 °C, indicating that the DBI modified silica/D-ESBR had lower rolling resistance without sacrificing wet skid resistance.