Twisted van der Waals Quantum Materials: Fundamentals, Tunability, and Applications.

Twisted van der Waals (vdW) quantum materials have emerged as a rapidly developing field of two-dimensional (2D) semiconductors. These materials establish a new central research area and provide a promising platform for studying quantum phenomena and investigating the engineering of novel optoelectronic properties such as single photon emission, nonlinear optical response, magnon physics, and topological superconductivity. These captivating electronic and optical properties result from, and can be tailored by, the interlayer coupling using moiré patterns formed by vertically stacking atomic layers with controlled angle misorientation or lattice mismatch. Their outstanding properties and the high degree of tunability position them as compelling building blocks for both compact quantum-enabled devices and classical optoelectronics. This paper offers a comprehensive review of recent advancements in the understanding and manipulation of twisted van der Waals structures and presents a survey of the state-of-the-art research on moiré superlattices, encompassing interdisciplinary interests. It delves into fundamental theories, synthesis and fabrication, and visualization techniques, and the wide range of novel physical phenomena exhibited by these structures, with a focus on their potential for practical device integration in applications ranging from quantum information to biosensors, and including classical optoelectronics such as modulators, light emitting diodes, lasers, and photodetectors. It highlights the unique ability of moiré superlattices to connect multiple disciplines, covering chemistry, electronics, optics, photonics, magnetism, topological and quantum physics. This comprehensive review provides a valuable resource for researchers interested in moiré superlattices, shedding light on their fundamental characteristics and their potential for transformative applications in various fields.

Multiparameter Estimation with Two-Qubit Probes in Noisy Channels.

This work compares the performance of single- and two-qubit probes for estimating several phase rotations simultaneously under the action of different noisy channels. We compute the quantum limits for this simultaneous estimation using collective and individual measurements by evaluating the Holevo and Nagaoka-Hayashi Cramér-Rao bounds, respectively. Several quantum noise channels are considered, namely the decohering channel, the amplitude damping channel, and the phase damping channel. For each channel, we find the optimal single- and two-qubit probes. Where possible we demonstrate an explicit measurement strategy that saturates the appropriate bound and we investigate how closely the Holevo bound can be approached through collective measurements on multiple copies of the same probe. We find that under the action of the considered channels, two-qubit probes show enhanced parameter estimation capabilities over single-qubit probes for almost all non-identity channels, i.e., the achievable precision with a single-qubit probe degrades faster with increasing exposure to the noisy environment than that of the two-qubit probe. However, in sufficiently noisy channels, we show that it is possible for single-qubit probes to outperform maximally entangled two-qubit probes. This work shows that, in order to reach the ultimate precision limits allowed by quantum mechanics, entanglement is required in both the state preparation and state measurement stages. It is hoped the tutorial-esque nature of this paper will make it easily accessible.

12.6 dB squeezed light at 1550 nm from a bow-tie cavity for long-term high duty cycle operation.

Squeezed states are an interesting class of quantum states that have numerous applications. This work presents the design, characterization, and operation of a bow-tie optical parametric amplifier (OPA) for squeezed vacuum generation. We report the high duty cycle operation and long-term stability of the system that makes it suitable for post-selection based continuous-variable quantum information protocols, cluster-state quantum computing, quantum metrology, and potentially gravitational wave detectors. Over a 50 hour continuous operation, the measured squeezing levels were greater than 10 dB with a duty cycle of 96.6%. Alternatively, in a different mode of operation, the squeezer can also operate 10 dB below the quantum noise limit over a 12 hour period with no relocks, with an average squeezing of 11.9 dB. We also measured a maximum squeezing level of 12.6 dB at 1550 nm. This represents one of the best reported squeezing results at 1550 nm to date for a bow-tie cavity. We discuss the design aspects of the experiment that contribute to the overall stability, reliability, and longevity of the OPA, along with the automated locking schemes and different modes of operation.

Quantum entanglement of angular momentum states with quantum numbers up to 10,010.

Photons with a twisted phase front carry a quantized amount of orbital angular momentum (OAM) and have become important in various fields of optics, such as quantum and classical information science or optical tweezers. Because no upper limit on the OAM content per photon is known, they are also interesting systems to experimentally challenge quantum mechanical prediction for high quantum numbers. Here, we take advantage of a recently developed technique to imprint unprecedented high values of OAM, namely spiral phase mirrors, to generate photons with more than 10,000 quanta of OAM. Moreover, we demonstrate quantum entanglement between these large OAM quanta of one photon and the polarization of its partner photon. To our knowledge, this corresponds to entanglement with the largest quantum number that has been demonstrated in an experiment. The results may also open novel ways to couple single photons to massive objects, enhance angular resolution, and highlight OAM as a promising way to increase the information capacity of a single photon.

High-performance Raman memory with spatio-temporal reversal.

A number of techniques exist to use an ensemble of atoms as a quantum memory for light. Many of these propose to use backward retrieval as a way to improve the storage and recall efficiency. We report on a demonstration of an off-resonant Raman memory that uses backward retrieval to achieve an efficiency of 65 ± 6% at a storage time of one pulse duration. The memory has a characteristic decay time of 60 µs, corresponding to a delay-bandwidth product of 160.

Violation of Bell's Inequality Using Continuous Variable Measurements.

A Bell inequality is a fundamental test to rule out local hidden variable model descriptions of correlations between two physically separated systems. There have been a number of experiments in which a Bell inequality has been violated using discrete-variable systems. We demonstrate a violation of Bell's inequality using continuous variable quadrature measurements. By creating a four-mode entangled state with homodyne detection, we recorded a clear violation with a Bell value of B=2.31±0.02. This opens new possibilities for using continuous variable states for device independent quantum protocols.

Coherent optical pulse sequencer for quantum applications.

The bandwidth and versatility of optical devices have revolutionized information technology systems and communication networks. Precise and arbitrary control of an optical field that preserves optical coherence is an important requisite for many proposed photonic technologies. For quantum information applications, a device that allows storage and on-demand retrieval of arbitrary quantum states of light would form an ideal quantum optical memory. Recently, significant progress has been made in implementing atomic quantum memories using electromagnetically induced transparency, photon echo spectroscopy, off-resonance Raman spectroscopy and other atom-light interaction processes. Single-photon and bright-optical-field storage with quantum states have both been successfully demonstrated. Here we present a coherent optical memory based on photon echoes induced through controlled reversible inhomogeneous broadening. Our scheme allows storage of multiple pulses of light within a chosen frequency bandwidth, and stored pulses can be recalled in arbitrary order with any chosen delay between each recalled pulse. Furthermore, pulses can be time-compressed, time-stretched or split into multiple smaller pulses and recalled in several pieces at chosen times. Although our experimental results are so far limited to classical light pulses, our technique should enable the construction of an optical random-access memory for time-bin quantum information, and have potential applications in quantum information processing.

A new entropic quantum correlation measure for adversarial systems.

Quantum correlation often refers to correlations exhibited by two or more local subsystems under a suitable measurement. These correlations are beyond the framework of classical statistics and the associated classical probability distribution. Quantum entanglement is the most well-known of such correlations and plays an important role in quantum information theory. However, there exist non-entangled states that still possess quantum correlations which cannot be described by classical statistics. One such measure that captures these non-classical correlations is discord. Here we introduce a new measure of quantum correlations which we call entropic accord that fits between entanglement and discord. It is defined as the optimised minimax mutual information of the outcome of the projective measurements between two parties. We show a strict hierarchy exists between entanglement, entropic accord and discord for two-qubit states. We study two-qubit states which shows the relationship between the three entropic quantities. In addition to revealing a class of correlations that are distinct from discord and entanglement, the entropic accord measure can be inherently more intuitive in certain contexts.

On the equivalence between squeezing and entanglement potential for two-mode Gaussian states.

The maximum amount of entanglement achievable under passive transformations by continuous-variable states is called the entanglement potential. Recent work has demonstrated that the entanglement potential is upper-bounded by a simple function of the squeezing of formation, and that certain classes of two-mode Gaussian states can indeed saturate this bound, though saturability in the general case remains an open problem. In this study, we introduce a larger class of states that we prove saturates the bound, and we conjecture that all two-mode Gaussian states can be passively transformed into this class, meaning that for all two-mode Gaussian states, entanglement potential is equivalent to squeezing of formation. We provide an explicit algorithm for the passive transformations and perform extensive numerical testing of our claim, which seeks to unite the resource theories of two characteristic quantum properties of continuous-variable systems.

Enhancing quantum teleportation efficacy with noiseless linear amplification.

Quantum teleportation constitutes a fundamental tool for various applications in quantum communication and computation. However, state-of-the-art continuous-variable quantum teleportation is restricted to moderate fidelities and short-distance configurations. This is due to unavoidable experimental imperfections resulting in thermal decoherence during the teleportation process. Here we present a heralded quantum teleporter able to overcome these limitations through noiseless linear amplification. As a result, we report a high fidelity of 92% for teleporting coherent states using a modest level of quantum entanglement. Our teleporter in principle allows nearly complete removal of loss induced onto the input states being transmitted through imperfect quantum channels. We further demonstrate the purification of a displaced thermal state, impossible via conventional deterministic amplification or teleportation approaches. The combination of high-fidelity coherent state teleportation alongside the purification of thermalized input states permits the transmission of quantum states over significantly long distances. These results are of both practical and fundamental significance; overcoming long-standing hurdles en route to highly-efficient continuous-variable quantum teleportation, while also shining new light on applying teleportation to purify quantum systems from thermal noise.

Approaching optimal entangling collective measurements on quantum computing platforms.

Entanglement is a fundamental feature of quantum mechanics and holds great promise for enhancing metrology and communications. Much of the focus of quantum metrology so far has been on generating highly entangled quantum states that offer better sensitivity, per resource, than what can be achieved classically. However, to reach the ultimate limits in multi-parameter quantum metrology and quantum information processing tasks, collective measurements, which generate entanglement between multiple copies of the quantum state, are necessary. Here, we experimentally demonstrate theoretically optimal single- and two-copy collective measurements for simultaneously estimating two non-commuting qubit rotations. This allows us to implement quantum-enhanced sensing, for which the metrological gain persists for high levels of decoherence, and to draw fundamental insights about the interpretation of the uncertainty principle. We implement our optimal measurements on superconducting, trapped-ion and photonic systems, providing an indication of how future quantum-enhanced sensing networks may look.

Generation of high-order optical vortices using directly machined spiral phase mirrors.

We report on the generation of high-order optical vortices by spiral phase mirrors (SPMs). The mirrors are produced by direct machining with a diamond tool and are shown to produce high-quality optical vortices with topological charges ranging from 1 to upwards of 100 at a wavelength of 532 nm. The direct machining technique is flexible and offers the promise of high-precision, large-diameter SPMs that are compatible with high optical powers.

Enhancing the precision limits of interferometric satellite geodesy missions.

Satellite geodesy uses the measurement of the motion of one or more satellites to infer precise information about the Earth's gravitational field. In this work, we consider the achievable precision limits on such measurements by examining approximate models for the three main noise sources in the measurement process of the current Gravitational Recovery and Climate Experiment (GRACE) Follow-On mission: laser phase noise, accelerometer noise and quantum noise. We show that, through time-delay interferometry, it is possible to remove the laser phase noise from the measurement, allowing for almost three orders of magnitude improvement in the signal-to-noise ratio. Several differential mass satellite formations are presented which can further enhance the signal-to-noise ratio through the removal of accelerometer noise. Finally, techniques from quantum optics have been studied, and found to have great promise for reducing quantum noise in other alternative mission configurations. We model the spectral noise performance using an intuitive 1D model and verify that our proposals have the potential to greatly enhance the performance of near-future satellite geodesy missions.

Backscatter tolerant squeezed light source for advanced gravitational-wave detectors.

We report on the performance of a dual-wavelength resonant, traveling-wave optical parametric oscillator to generate squeezed light for application in advanced gravitational-wave interferometers. Shot noise suppression of 8.6±0.8 dB was measured across the detection band of interest to Advanced LIGO, and controlled squeezing measured over 5900 s. Our results also demonstrate that the traveling-wave design has excellent intracavity backscattered light suppression of 47 dB and incident backscattered light suppression of 41 dB, which is a crucial design issue for application in advanced interferometers.

Photothermally induced transparency.

Induced transparency is a common but remarkable effect in optics. It occurs when a strong driving field is used to render an otherwise opaque material transparent. The effect is known as electromagnetically induced transparency in atomic media and optomechanically induced transparency in systems that consist of coupled optical and mechanical resonators. In this work, we introduce the concept of photothermally induced transparency (PTIT). It happens when an optical resonator exhibits nonlinear behavior due to optical heating of the resonator or its mirrors. Similar to the established mechanisms for induced transparency, PTIT can suppress the coupling between an optical resonator and a traveling optical field. We further show that the dispersion of the resonator can be modified to exhibit slow or fast light. Because of the relatively slow thermal response, we observe the bandwidth of the PTIT to be 2π × 15.9 Hz, which theoretically suggests a group velocity of as low as 5 m/s.

Supertransport of excitons in atomically thin organic semiconductors at the 2D quantum limit.

Long-range and fast transport of coherent excitons is important for the development of high-speed excitonic circuits and quantum computing applications. However, most of these coherent excitons have only been observed in some low-dimensional semiconductors when coupled with cavities, as there are large inhomogeneous broadening and dephasing effects on the transport of excitons in their native states in materials. Here, by confining coherent excitons at the 2D quantum limit, we first observed molecular aggregation-enabled 'supertransport' of excitons in atomically thin two-dimensional (2D) organic semiconductors between coherent states, with a measured high effective exciton diffusion coefficient of ~346.9 cm2/s at room temperature. This value is one to several orders of magnitude higher than the values reported for other organic molecular aggregates and low-dimensional inorganic materials. Without coupling to any optical cavities, the monolayer pentacene sample, a very clean 2D quantum system (~1.2 nm thick) with high crystallinity (J-type aggregation) and minimal interfacial states, showed superradiant emission from Frenkel excitons, which was experimentally confirmed by the temperature-dependent photoluminescence (PL) emission, highly enhanced radiative decay rate, significantly narrowed PL peak width and strongly directional in-plane emission. The coherence in monolayer pentacene samples was observed to be delocalised over ~135 molecules, which is significantly larger than the values (a few molecules) observed for other organic thin films. In addition, the supertransport of excitons in monolayer pentacene samples showed highly anisotropic behaviour. Our results pave the way for the development of future high-speed excitonic circuits, fast OLEDs, and other optoelectronic devices.

Atomic localization of quantum emitters in multilayer hexagonal boron nitride.

The recent discovery of single-photon emitting defects hosted by the two-dimensional wide band gap semiconductor hexagonal boron nitride (hBN) has inspired a great number of experiments. Key characteristics of these quantum emitters are their capability to operate at room temperature with a high luminosity. In spite of large theoretical and experimental research efforts, the exact nature of the emission remains unresolved. In this work we utilize layer-by-layer etching of multilayer hBN to localize the quantum emitters with atomic precision. Our results suggest the position of the emitters correlates with the fabrication method: emitters formed under plasma treatment are always in close proximity to the crystal surface, while emitters created under electron irradiation are distributed randomly throughout the entire crystal. This disparity could be traced back to the lower kinetic energy of the ions in the plasma compared to the kinetic energy of the electrons in the particle accelerator. The emitter distance to the surface also correlates with the excited state lifetime: near-surface emitters have a shorter one compared to emitters deep within the crystal. Finite-difference time-domain and density functional theory simulations show that optical and electronic effects are not responsible for this difference, indicating effects such as coupling to surface defects or phonons might cause the reduced lifetime. Our results pave a way toward identification of the defect, as well as engineering the emitter properties.

Radiation tolerance of two-dimensional material-based devices for space applications.

Characteristic for devices based on two-dimensional materials are their low size, weight and power requirements. This makes them advantageous for use in space instrumentation, including photovoltaics, batteries, electronics, sensors and light sources for long-distance quantum communication. Here we present a comprehensive study on combined radiation effects in Earth's atmosphere on various devices based on these nanomaterials. Using theoretical modeling packages, we estimate relevant radiation levels and then expose field-effect transistors, single-photon sources and monolayers as building blocks for future electronics to γ-rays, protons and electrons. The devices show negligible change in performance after the irradiation, suggesting robust suitability for space use. Under excessive γ-radiation, however, monolayer WS2 shows decreased defect densities, identified by an increase in photoluminescence, carrier lifetime and a change in doping ratio proportional to the photon flux. The underlying mechanism is traced back to radiation-induced defect healing, wherein dissociated oxygen passivates sulfur vacancies.

Fabrication of ultrahigh-precision hemispherical mirrors for quantum-optics applications.

High precision, high numerical aperture mirrors are desirable for mediating strong atom-light coupling in quantum optics applications and can also serve as important reference surfaces for optical metrology. In this work we demonstrate the fabrication of highly-precise hemispheric mirrors with numerical aperture NA = 0.996. The mirrors were fabricated from aluminum by single-point diamond turning using a stable ultra-precision lathe calibrated with an in-situ white-light interferometer. Our mirrors have a diameter of 25 mm and were characterized using a combination of wide-angle single-shot and small-angle stitched multi-shot interferometry. The measurements show root-mean-square (RMS) form errors consistently below 25 nm. The smoothest of our mirrors has a RMS error of 14 nm and a peak-to-valley (PV) error of 88 nm, which corresponds to a form accuracy of λ/50 for visible optics.

Integrated photonic platform for quantum information with continuous variables.

Integrated quantum photonics provides a scalable platform for the generation, manipulation, and detection of optical quantum states by confining light inside miniaturized waveguide circuits. Here, we show the generation, manipulation, and interferometric stage of homodyne detection of nonclassical light on a single device, a key step toward a fully integrated approach to quantum information with continuous variables. We use a dynamically reconfigurable lithium niobate waveguide network to generate and characterize squeezed vacuum and two-mode entangled states, key resources for several quantum communication and computing protocols. We measure a squeezing level of - 1.38 ± 0.04 dB and demonstrate entanglement by verifying an inseparability criterion I = 0.77 ± 0.02 < 1. Our platform can implement all the processes required for optical quantum technology, and its high nonlinearity and fast reconfigurability make it ideal for the realization of quantum computation with time encoded continuous-variable cluster states.