Novel ternary organic resistive switching memory doped with bipolar materials.

Organic resistive switching memory (ORSM) shows great potential for neotype memory devices due to the preponderances of simple architecture, low power consumption, high switching speed and feasibility of large-area fabrication. Herein, solution-processed ternary ORSM devices doped with bipolar materials were achieved with high ON/OFF ratio and outstanding device stability. The resistive switching performance was effectively ameliorated by doping two bipolar materials (DpAn-InAc and DpAn-5BzAc) in different blending concentration into the PVK:OXD-7 donor-accepter system. Compared with the binary system (PVK: 30 wt% OXD-7), the ON/OFF ratios of the ternary devices doped with 6 wt% DpAn-5BzAc were greatly increased from 7.91 × 102to 4.98 × 104, with the operating voltage (∣Vset-Vreset∣) declined from 4.90 V to 2.25 V, respectively. Additionally, the stability of resistance state and uniformity of operating voltage were also significantly optimized for the ternary devices. For comparison, ternary devices doped with DpAn-InAc have been explored, which also achieved improved resistive switching behavior. A detailed analysis of electrical characteristics and the internal charge transfer properties of ORSM was performed to unveil the performance enhancement in ternary devices. Results indicate that the use of bipolar materials favors the efficient operation of OSRMs with proper energy level alignment and effective charge transfer.

A Review of Recent Advances in Vital Signals Monitoring of Sports and Health via Flexible Wearable Sensors.

In recent years, vital signals monitoring in sports and health have been considered the research focus in the field of wearable sensing technologies. Typical signals include bioelectrical signals, biophysical signals, and biochemical signals, which have applications in the fields of athletic training, medical diagnosis and prevention, and rehabilitation. In particular, since the COVID-19 pandemic, there has been a dramatic increase in real-time interest in personal health. This has created an urgent need for flexible, wearable, portable, and real-time monitoring sensors to remotely monitor these signals in response to health management. To this end, the paper reviews recent advances in flexible wearable sensors for monitoring vital signals in sports and health. More precisely, emerging wearable devices and systems for health and exercise-related vital signals (e.g., ECG, EEG, EMG, inertia, body movements, heart rate, blood, sweat, and interstitial fluid) are reviewed first. Then, the paper creatively presents multidimensional and multimodal wearable sensors and systems. The paper also summarizes the current challenges and limitations and future directions of wearable sensors for vital typical signal detection. Through the review, the paper finds that these signals can be effectively monitored and used for health management (e.g., disease prediction) thanks to advanced manufacturing, flexible electronics, IoT, and artificial intelligence algorithms; however, wearable sensors and systems with multidimensional and multimodal are more compliant.

1st-Stokes and 2nd-Stokes dual-wavelength operation and mode-locking modulation in diode-side-pumped Nd:YAG/BaWO4 Raman laser.

1st-Stokes and 2nd-Stokes dual-wavelength operation within a diode-side-pumped Q-switched Nd:YAG/BaWO(4) intracavity Raman laser was realized. Using an output coupler of transmission of 3.9% at 1180 nm and transmission of 60.08% at 1325 nm, the maximum output power of 8.30 W and 2.84 W at a pulse repetition rate of 15 kHz for the 1st Stokes and the 2nd Stokes laser were obtained, respectively. The corresponding optical conversion efficiency from diode laser to the 1st Stokes and 2nd Stokes laser are 5.0% and 1.4%, respectively. With the pump power of 209 W and a pulse repetition rate of 15 kHz, the 1st Stokes and the 2nd Stokes pulse widths were 20.5 ns and 5.8 ns, respectively. The stable simultaneous Q-switching and mode locking of the 2nd Stokes laser without mode locking component was obtained at the pump power of about 29~82 W. The estimated mode-locked pulse width was approximately 31 ps at the pump power of 50 W and a pulse repetition rate of 15 kHz.

Theoretical and experimental studies on output characteristics of an intracavity KTA OPO.

An acousto-optically Q-switched Nd:YVO(4)/KTiOAsO(4) (KTA) intracavity optical parametric oscillator (OPO) is efficiently realized in singly resonated scheme. With an end-pumping diode power of 25.9 W, output signal (1535 nm) power of 3.77 W and idler power (3467 nm) of 1.18 W are obtained at a pulse repetition rate of 50 kHz. A rate-equation model is set up to simulate the output power and time characteristics of both signal and idler waves. And both the numerical and experimental results show that the idler pulse width is shorter than the signal one in a singly resonant OPO.

Simultaneous dual-wavelength operation of Nd:YVO4 self-Raman laser at 1524 nm and undoped GdVO4 Raman laser at 1522 nm.

A diode-pumped, actively Q-switched dual-wavelength laser employing Nd:YVO(4) self-Raman emission at 1524 nm and undoped GdVO(4) Raman emission at 1522 nm is demonstrated. With a pump power of 21.5 W and pulse repetition frequency of 20 kHz, a maximum dual-wavelength output power of 1.62 W was obtained, comprising a 0.54 W, 1522 nm Raman component and 1.08 W, 1524 nm self-Raman component. The corresponding dual-wavelength Raman pulse width was 5.6 ns. The experimental results indicate that this laser, with quite small wavelength separation, was effective by virtue of simultaneous self-Raman and Raman shifts.

Second-Stokes dual-wavelength operation at 1321 and 1325 nm ceramic Nd:YAG/BaWO4 Raman laser.

A diode-pumped, actively Q-switched second-Stokes dual-wavelength laser employing ceramic Nd:YAG as the gain medium and BaWO(4) as the Raman medium is demonstrated. The dual-wavelength Raman laser emission at 1321 and 1325 nm is based on the dual-wavelength fundamental laser emission at 1061 and 1064 nm. With a pump power of 18.4 W and pulse repetition frequency of 15 kHz, a maximum dual-wavelength output power of 1.67 W was obtained, comprising a 0.75 W, 1321 nm laser component and a 0.92 W, 1325 nm laser component. The corresponding dual-wavelength second-Stokes pulse width was 2.9 ns.

New Method for Preparing Small-Caliber Artificial Blood Vessel with Controllable Microstructure on the Inner Wall Based on Additive Material Composite Molding.

The diameter of most blood vessels in cardiovascular and peripheral vascular system is less than 6 mm. Because the inner diameter of such vessels is small, a built-in stent often leads to thrombosis and other problems. It is an important goal to replace it directly with artificial vessels. This paper creatively proposed a preparation method of a small-diameter artificial vascular graft which can form a controllable microstructure on the inner wall and realize a multi-material composite. On the one hand, the inner wall of blood vessels containing direct writing structure is constructed by electrostatic direct writing and micro-imprinting technology to regulate cell behavior and promote endothelialization; on the other hand, the outer wall of blood vessels was prepared by electrospinning PCL to ensure the stability of mechanical properties of composite grafts. By optimizing the key parameters of the graft, a small-diameter artificial blood vessel with controllable microstructure on the inner wall is finally prepared. The corresponding performance characterization experimental results show that it has advantages in structure, mechanical properties, and promoting endothelialization.

Efficient and chromaticity-stable flexible white organic light-emitting devices based on organic-inorganic hybrid color-conversion electrodes.

We have developed a novel organic-inorganic hybrid color conversion electrode composed of Ag NWs/poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) via a solution process, which is the first report on a color conversion electrode for applications in flexible optoelectronics. Using the Ag NWs/MEH-PPV composite film as the anode on polyethylene terephthalate substrate and combined with a blue organic light emitting devices (OLEDs) unit employing bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl)iridium(iii)) (Flrpic) in 1,3-bis(carbazol-9-yl)benzene (mCP) as the emitting layer, a highly efficient and chromaticity-stable color-conversion flexible white OLEDs (WOLEDs) is achieved with a maximum current efficiency of 20.5 cd A-1. To the best of our knowledge, this is the highest efficiency reported for color-conversion based flexible WOLEDs. Our work provides an approach to achieving high-performance flexible WOLEDs devices and demonstrates great potential for lighting and display applications.