Sulfate Ions Induced Concave Porous S-N Co-Doped Carbon Confined FeCx Nanoclusters with Fe-N4 Sites for Efficient Oxygen Reduction in Alkaline and Acid Media.

To improve the catalytic activity of the catalysts, it is key to intensifying the intrinsic activity of active sites or increasing the exposure of accessible active sites. In this work, an efficient oxygen reduction electrocatalyst is designed that confines plentiful FeCx nanoclusters with Fe-N4 sites in a concave porous S-N co-doped carbon matrix, readily accessible for the oxygen reduction reaction (ORR). Sulfate ions react with the carbon derived from ZIF-8 at high temperatures, leading to the shrinkage of the carbon framework and then forming a concave structure with abundant macropores and mesopores with S incorporation. Such an architecture promotes the exposure of active sites and accelerates remote mass transfer. As a result, the catalyst (Fe/S-NC) with a large number of C-S-C, Fe-N4 , and FeCx nanoclusters presents impressive ORR activity and stability. In alkaline media, the half-wave potential of the best catalyst (Fe/S2 -NC) is 0.91 V, which far exceeds that of commercial platinum carbon (0.85 V), while in acidic media the half-wave potential reaches 0.784 V, comparable to platinum carbon (0.812 V). Furthermore, for the zinc-air battery, the outstanding peak power density of Fe/S2 -NC (170 mW cm-2 ) superior to platinum carbon (108 mW cm-2 ) also highlights its great application potential.

Sedimentary records of environmental evolution in Dongzhai Port mangrove swamps (South China) over the last hundred years: Insights from corrections of grain-size effects.

Mangrove sediments play a vital role in the biogeochemical processes of elements by behaving as both sources and/or sink for nutrients and trace metals. Under the combined impacts of grain-size effects and human activities, it is difficult to accurately assess the sources and degree of pollutants. For this purpose, two cores were collected from a mangrove swamps of Dongzhai Port (South China) and analyzed for temporal distributions of grain size, nutrients, major and trace elements, and 210Pb activities. Due to the significant vertical variation of grain size with depth, linear regression analysis was conducted based on trace metals (i.e., Pb, Cr, Ni, Cu, Cd, Zn) and normalized element Al to reconstruct local environmental background. The results showed that the contents of Cu, Cd, and Zn in the surface layers exhibited significantly increasing trends since the 1980s, with maximum contents of 9.06, 0.16, and 228.66 µg g-1, and their enrichment factors up to 1.52, 1.40, and 1.50, respectively. It should be attributed to shrimp farming and domestic sewage, indicating slight anthropogenic inputs. The evolution process was divided into three stages in Dongzhai Port over the last 100 years: before 1980 AD, 1980-2000 AD, and from 2000 AD to the present, corresponding to the stages of natural deposition, domestic pollution, and aquaculture pollution, respectively.

Stabilizing Fe-N-C Catalysts as Model for Oxygen Reduction Reaction.

The highly efficient energy conversion of the polymer-electrolyte-membrane fuel cell (PEMFC) is extremely limited by the sluggish oxygen reduction reaction (ORR) kinetics and poor electrochemical stability of catalysts. Hitherto, to replace costly Pt-based catalysts, non-noble-metal ORR catalysts are developed, among which transition metal-heteroatoms-carbon (TM-H-C) materials present great potential for industrial applications due to their outstanding catalytic activity and low expense. However, their poor stability during testing in a two-electrode system and their high complexity have become a big barrier for commercial applications. Thus, herein, to simplify the research, the typical Fe-N-C material with the relatively simple constitution and structure, is selected as a model catalyst for TM-H-C to explore and improve the stability of such a kind of catalysts. Then, different types of active sites (centers) and coordination in Fe-N-C are systematically summarized and discussed, and the possible attenuation mechanism and strategies are analyzed. Finally, some challenges faced by such catalysts and their prospects are proposed to shed some light on the future development trend of TM-H-C materials for advanced ORR catalysis.