RESUMEN
The complete transformation from narrow peak emission of Eu3+ to broadband emission of Eu2+ was first realized in La1-xSr2+xAl1-xSixO5:Eu series solutions relying on crystal field engineering and adjustment of synthesis parameters. The original red phosphor La0.97Sr2AlO5:0.03Eu3+peaks at 703 nm originated from 5D0 â7F4 transition of Eu3+ under 395 nm excitation. As the x value regularly increased, Sr2SiO4-type green phosphor La0.17Sr2.8Al0.2Si0.8O5:0.03Eu2+ was synthesized at x = 0.8, which can be efficiently excited by UV/blue light chips. Moreover, when x > 0.975, Sr3SiO5:Eu2+ type broadband orange phosphor Sr2.945Al0.025Si0.975O5:0.03Eu2+ with excellent thermal stability (91.3% peak intensity at 150 °C) was obtained. Variations in the crystal structure, phase, and luminescence properties were studied in detail. We hope this work can provide a reference that solid solution between distinct but structurally related systems is a strategy to explore the possible phosphors for phosphor-converted light-emitting diodes.
RESUMEN
Extensive research has gone into modifying the chemical composition of phosphors to achieve desirable optical properties. Here, oxynitride phosphors K2Ba6.72Si16O40-1.5yNy:0.28Eu2+ were synthesized by introducing N3- (y) into a K2Ba6.72Si16O40:0.28Eu2+ lattice. An uneven shrinking of the cell parameters a, b, and c was observed through a combination of X-ray diffraction studies and Rietveld refinements. This shrinking caused a large centroid shift (εc) and splitting of the 5d energy level (εcfs), thus inducing the broadening of the excitation spectra (104 â 127 nm, y = 0 â y = 12) and the red shift of the emission spectra (501 â 543 nm, y = 0 â y = 12). The modified series of samples have a broad excitation spectrum, suitable of use in UV, near-UV, and blue light-emitting LEDs. In addition, the optimal sample, K2Ba6.72Si16O31N6:0.28Eu2+, benefits from an increased activation energy and thermal stability.