Control of physical properties in BiFeO3nanoparticles via Sm3+and Co2+ion doping.

Highly crystalline BiFeO3(BFO), Bi0.97Sm0.03FeO3(Sm-BFO) and BiFe0.97Co0.03O3(Co-BFO) nanoparticles (NPs) were utilized as potential magnetic hyperthermia agents at two different frequencies in the radiofrequency (RF) range, and the effect of Sm3+and Co2+ion doping on the physical properties of the material was examined. The thermal behaviour of the as-prepared powders disclosed that the crystallization temperature of the powders is affected by the incorporation of the dopants into the BFO lattice and the Curie transition temperature is decreased upon doping. Vibrational analysis confirmed the formation of the R3c phase in all compounds through the characteristic FT-IR absorbance bands assigned to O-Fe-O bending vibration and Fe-O stretching of the octahedral FeO6group in the perovskite, as well as through Raman spectroscopy. The shift of the Raman-active phonon modes in Sm-BFO and Co-BFO NPs indicated structural distortion of the BFO lattice, which resulted in increased local polarization and enhanced visible light absorption. The aqueous dispersion of Co-BFO NPs showed the highest magnetic hyperthermia performance at 30 mT/765 kHz, entering the therapeutic temperature window for cancer treatment, whereas the heating efficiency of all samples was increased with increasing frequency from 375 to 765 kHz, making our doped nanoparticles to be suitable candidates for potential biomedical applications.

CIDACC: Chlorella vulgaris image dataset for automated cell counting.

This CIDACC dataset was created to determine the cell population of Chlorella vulgaris microalga during cultivation. Chlorella vulgaris has diverse applications, including use as food supplement, biofuel production, and pollutant removal. High resolution images were collected using a microscope and annotated, focusing on computer vision and machine learning models creation for automatic Chlorella cell detection, counting, size and geometry estimation. The dataset comprises 628 images, organized into hierarchical folders for easy access. Detailed segmentation masks and bounding boxes were generated using external tools enhancing the dataset's utility. The dataset's efficacy was demonstrated through preliminary experiments using deep learning architecture such as object detection and localization algorithms, as well as image segmentation algorithms, achieving high precision and accuracy. This dataset is a valuable tool for advancing computer vision applications in microalgae research and other related fields. The dataset is particularly challenging due to its dynamic nature and the complex correlations it presents across various application domains, including cell analysis in medical research. Its intricacies not only push the boundaries of current computer vision algorithms but also offer significant potential for advancements in diverse fields such as biomedical imaging, environmental monitoring, and biotechnological innovations.

The dome of Rotunda in Thessaloniki: Investigation of a multi-pictorial phase wall painting through analytical methods.

The present study focuses on the investigation of the successive pictorial phases of the wall painting which survives on the missing eastern part of the magnificent mosaic composition in the interior of Rotunda, Thessaloniki, Greece. Rotunda, a circular domed monumental building, was constructed in the early 4th century AD and it is included in the UNESCO World Heritage List. Characterization analysis was performed by means of microscopic, spectroscopic and crystallographic techniques, in order to identify the technological features of the wall painting and the materials used, to document the initial Byzantine pictorial phase -known from the archaeological research- along with the overpaintings attributed to the 19th and 20th centuries. In this framework, the collected samples were studied with optical microscopy, Fourier transform infrared micro-spectroscopy, scanning electron microscopy, X-ray diffractometry and X-ray photoelectron spectroscopy. Among the detected materials and pigments (including zinc oxide, barium sulfate, red lead, green earth, Prussian blue, emerald green, ultramarine and cuprite), the use of brass powder for false gilding purposes was detected, which is a material rarely used for mural applications.

Effect of novel charcoal-containing whitening toothpaste and mouthwash on color change and surface morphology of enamel.

PURPOSE: The aim of this in vitro study was to investigate the effectiveness of a novel charcoal-containing whitening toothpaste and a mouthwash on tooth color change and the alterations of enamel that may be induced after toothbrushing, corresponding to a 90-day period. MATERIALS AND METHODS: Forty human canines were used, stained with coffee, and divided into four groups (n = 10) as follows: Group 1 (control) submitted to toothbrushing with deionized water, Group 2 with a regular toothpaste, Group 3 with a whitening toothpaste (1% charcoal), and Group 4 with the same whitening toothpaste in combination with a mouthwash (1% charcoal and 0.5% H2O2). After the treatments, ΔΕ of the teeth was evaluated using an ultraviolet/Vis spectrophotometer, whereas the changes in surface morphology were observed by means of a confocal microscope. RESULTS: The whitening toothpaste increased significantly ΔΕ (40.5%) compared to the control group (P < 0.001). In addition, the tested whitening toothpaste also increased ΔΕ (17.7%) compared to the regular toothpaste (P = 0.023). The whitening toothpaste presented smoother surfaces after toothbrushing, but more heterogeneous with numerous large craters, whereas the whitening mouthwash did not influence surface morphology changes. CONCLUSIONS: Charcoal-containing toothpastes may enhance the whitening of the teeth, but they should be used carefully due to changes that may induce on enamel. The patients should consult a dental professional for proper use. A charcoal-containing mouthwash in combination with whitening toothpastes probably cannot offer additional whitening effect.

Study of dental zirconia reinforced lithium silicate for its use as a personal accidental dosimeter.

A recently introduced material for dental restorations, Zirconia reinforced Lithium Silicate (ZLS), is examined for its properties, in order to be used as a personal accidental thermoluminescence dosimeter. For this purpose, its main thermoluminescence characteristics are studied, such as its sensitivity, signal reproducibility, fading, dose response and lower detectable dose limit. Furthermore, the material is characterized by means of microscopic, spectroscopic and crystallographic techniques. The results propose that ZLS is promising to be used as a personal accidental thermoluminescence dosimeter for post-irradiation detection, with single aliquot protocols.

Unraveling the materials and techniques of post-Byzantine wall paintings: Is there a sole pictorial phase at the catholicon of Stomion, Central Greece?

Saint Demetrius of Stomion is a historical monastery placed in the geographical area of Larissa town, Greece, with a remarkable presence from its founding until nowadays. The monastery's present catholicon (main church) has been dated in the 16th century and its surviving wall paintings were constructed in 1758. In addition to the characterization of the materials applied, the purpose of this study is to determine the existence of a sole pictorial phase, that of the mid-18th century, or the occurrence of overpaintings. Additionally, the present study aims to begin the establishment of the documentation of materials and techniques of the late post-Byzantine iconographic guilds, which acted in Central and Northern Greece. The collected samples were analyzed by means of microscopic, spectroscopic and thermogravimetric methods. The use of fresco technique is implied by the major participation of calcium carbonate in all of the painting layers, its main contribution in the plaster layers and the microstratigraphic analysis of the samples' cross-sections, while the scarce and local presence of a proteinaceous material implies the limited use of egg-tempera technique for the highlights. The pigment analysis shows that mostly traditional pigments were used, including cinnabar, ferrous pigments (ochre, sienna, umber), minium, Naples yellow, massicot/litharge, green earth (celadonite), malachite, carbon and bone black, calcite, kaolinite and lead white. The absence of modern pigments, the consistency of all samples regarding microstratigraphy and applied materials, and the lack of the extensive use of an organic medium, strongly suggest the lack of overpaintings.