Ultrafast surface carrier dynamics in the topological insulator Bi2Te3.

We discuss the ultrafast evolution of the surface electronic structure of the topological insulator Bi(2)Te(3) following a femtosecond laser excitation. Using time and angle-resolved photoelectron spectroscopy, we provide a direct real-time visualization of the transient carrier population of both the surface states and the bulk conduction band. We find that the thermalization of the surface states is initially determined by interband scattering from the bulk conduction band, lasting for about 0.5 ps; subsequently, few picoseconds are necessary for the Dirac cone nonequilibrium electrons to recover a Fermi-Dirac distribution, while their relaxation extends over more than 10 ps. The surface sensitivity of our measurements makes it possible to estimate the range of the bulk-surface interband scattering channel, indicating that the process is effective over a distance of 5 nm or less. This establishes a correlation between the nanoscale thickness of the bulk charge reservoir and the evolution of the ultrafast carrier dynamics in the surface Dirac cone.

Interaction of localized electronic states with the conduction band: band anticrossing in II-VI semiconductor ternaries

We report a strongly nonlinear pressure dependence of the band gaps and large downward shifts of the conduction band edges as functions of composition in ZnS xTe (1-x) and ZnSe (y)Te (1-y) alloys. The dependencies are explained by an interaction between localized A1 symmetry states of S or Se atoms and the extended states of the ZnTe matrix. These results, combined with previous studies of III-N-V materials define a new, broad class of semiconductor alloys in which the introduction of highly electronegative atoms leads to dramatic modifications of the conduction band structure. The modifications are well described by the recently introduced band anticrossing model.

Tuning a Schottky barrier in a photoexcited topological insulator with transient Dirac cone electron-hole asymmetry.

The advent of Dirac materials has made it possible to realize two-dimensional gases of relativistic fermions with unprecedented transport properties in condensed matter. Their photoconductive control with ultrafast light pulses is opening new perspectives for the transmission of current and information. Here we show that the interplay of surface and bulk transient carrier dynamics in a photoexcited topological insulator can control an essential parameter for photoconductivity-the balance between excess electrons and holes in the Dirac cone. This can result in a strongly out of equilibrium gas of hot relativistic fermions, characterized by a surprisingly long lifetime of more than 50 ps, and a simultaneous transient shift of chemical potential by as much as 100 meV. The unique properties of this transient Dirac cone make it possible to tune with ultrafast light pulses a relativistic nanoscale Schottky barrier, in a way that is impossible with conventional optoelectronic materials.

Spectroscopic signatures of novel oxygen-defect complexes in stoichiometrically controlled CdSe.

Growth of single crystals of CdSe with oxygen, introduced by stoichiometric control to suppress the formation of native Se and Cd vacancies, generates oxygen centers replacing Cd (O Cd) rather than Se (O Se) as expected. This antisite substitution is unambiguously singled out by the host isotope fine structure of the nearest neighbor (NN) Se atoms in the localized vibrational modes (LVMs) of O Cd. When the stoichiometry control favors the formation of Cd vacancies, three infrared signatures gamma1, gamma2 and gamma3 appear ascribable to the LVMs of O Se in association with a Cd vacancy in the NN position as (O Se-V Cd) centers. Polarization measurements establish the monoclinic Cs symmetry for these centers. As a function of temperature, they display a remarkable two-step symmetry transformation, Cs-->C3v-->Td, due to the dynamic switching of the O Se-V Cd dangling bond.

Stoichiometry driven impurity configurations in compound semiconductors.

Precise stoichiometry and departures therefrom in the composition of the tetrahedrally coordinated compound semiconductors allow impurity incorporation in more than one configuration. Ultrahigh resolution infrared spectroscopy of CdTe:O at low temperatures reveals a unique sharp doublet associated with the local vibrational modes of OTe in a (OTe-VCd) complex with nearest neighbor Cd vacancy VCd and a single sharp line attributed to the local vibrational mode of OTe in a perfect CdTe. The uniaxial (C3v) symmetry of (OTe-VCd) transforms to Td symmetry at T* approximately 300 K, acquired due to an increasing rate of dynamic switching of the "OTe-VCd" dangling bond in which the vacancy and its three next nearest neighbor Cd cations exchange positions as temperature (T) approaches T*; for T>or=T*, the doublet thus transforms into a single, triply degenerate line.

Optical phase conjugation in a magnetic photorefractive semiconductor CdMnTe.

Magneto-optical phase conjugation was performed in a diluted magnetic photorefractive semiconductor crystal CdMnTe under an applied magnetic field. The magnetic field removes time-reversal symmetry and quenches orthogonal components of the phase-conjugate signal for selected field strengths. The experimental results as functions of magnetic field and incident polarization angle are in good agreement with coupled-mode theory with transmission gratings during magneto-photorefractive mixing.