Dip-coating decoration of Ag2O nanoparticles on SnO2 nanowires for high-performance H2S gas sensors.

SnO2 nanowires (NWs) are used in gas sensors, but their response to highly toxic gas H2S is low. Thus, their performance toward the effective detection of low-level H2S in air should be improved for environmental-pollution control and monitoring. Herein, Ag2O nanoparticle decorated SnO2 NWs were prepared by a simple on-chip growth and subsequent dip-coating method. The amount of decorated Ag2O nanoparticles on the surface of SnO2 NWs was modified by changing the concentration of AgNO3 solution and/or dipping times. Gas-sensing measurements were conducted at various working temperatures (200-400 °C) toward different H2S concentrations ranging within 0.1-1 ppm. The selectivity of Ag2O-decorated SnO2 NW sensors for ammonia and hydrogen gases was tested. Results confirmed that the Ag2O-decorated SnO2 NW sensors had excellent response, selectivity, and reproducibility. The gas-sensing mechanism was interpreted under the light of energy-band bending by sulfurization, which converted the p-n junction into n-n, thereby significantly enhancing the sensing performance.

An effective H2S sensor based on SnO2 nanowires decorated with NiO nanoparticles by electron beam evaporation.

The highly toxic hydrogen sulphide (H2S) present in air can cause negative effects on human health. Thus, monitoring of this gas is vital in gas leak alarms and security. Efforts have been devoted to the fabrication and enhancement of the H2S-sensing performance of gas sensors. Herein, we used electron beam evaporation to decorate nickel oxide (NiO) nanoparticles on the surface of tin oxide (SnO2) nanowires to enhance their H2S gas-sensing performance. The synthesised NiO-SnO2 materials were characterised by field-emission scanning electron microscopy, transmission electron microscopy and energy dispersive spectroscopy analysis. H2S gas-sensing characteristics were measured at various concentrations (1-10 ppm) at 200-350 °C. The results show that with effective decoration of NiO nanoparticles, the H2S gas-sensing characteristics of SnO2 nanowires are significantly enhanced by one or two orders compared with those of the bare material. The sensors showed an effective response to low-level concentrations of H2S in the range of 1-10 ppm, suitable for application in monitoring of H2S in biogas and in industrial controls. We also clarified the sensing mechanism of the sensor based on band structure and sulphurisation process.