RESUMEN
Cold and diluted wastewater is a major challenge for nitrogen removal at wastewater treatment plants. The moving-bed biofilm reactor (MBBR) process has proven suitable for nitrogen removal under these conditions and several full-scale plants have been in operation for more than 20 years. These plants are still performing well, even at above design loads. Recently some of these plants have been evaluated for their low-temperature performance. In general, the results showed that temperatures down to 5 °C only had a minor impact on observed nitrification and denitrification rates. Higher dissolved oxygen concentrations can boost nitrification rates and are used as a tool to increase rates at low temperatures, thus partially compensating for the temperature effect. Post-denitrification rates were boosted by a controlled increase in carbon-to-nitrogen ratios at low temperatures. MBBR processes with combined pre- and post-denitrification are recommended for nitrogen-removal plants operating at low temperatures. Design recommendations and examples of flowsheets are given.
Asunto(s)
Biopelículas , Desnitrificación , Temperatura , Nitrógeno , Reactores Biológicos , Nitrificación , Noruega , Eliminación de Residuos LíquidosRESUMEN
This research elucidates the pollutants (nutrients and carbon) removal performance and nitrous oxide (N2O) emissions of two pilot plants. Specifically, a University of Cape Town (UCT) Membrane Bioreactor (MBR) plant and an Integrated Fixed Film Activated Sludge (IFAS)-UCT-MBR plant were investigated. The plants were fed with real wastewater augmented with acetate and glycerol in order to control the influent carbon nitrogen ratio (C/N). The short-term effect of the inlet C/N ratio variation (C/Nâ¯=â¯5 mgCOD/mgN and C/Nâ¯=â¯10 mgCOD/mgN) on the behaviour of both plants was investigated. The results showed that the IFAS-UCT-MBR configuration provided the best performance in terms of pollutants removal at the two investigated C/N ratios. Furthermore, the lowest N2O emission (with respect to the influent nitrogen) was observed in the IFAS-UCT-MBR configuration, thus suggesting a potential beneficial effect of the biofilm in the emission reduction. However, the membrane of the IFAS-UCT-MBR showed a greater fouling tendency compared to the UCT-MBR configuration. This result, likely related to the biofilm detached from carriers, could seriously affect the indirect GreenHouse Gas emissions due to the increase of the energy requirement for permeate extraction with the increase of membrane fouling.
Asunto(s)
Reactores Biológicos , Aguas del Alcantarillado , Eliminación de Residuos Líquidos , Membranas Artificiales , Nitrógeno , Aguas ResidualesRESUMEN
The present paper reports the results of a nitrous oxide (N2O) production investigation in a moving bed based integrated fixed film activated sludge (IFAS) membrane bioreactor (MBR) pilot plant designed in accordance with the University of Cape Town layout for biological phosphorous removal. Gaseous and liquid samples were collected in order to measure the gaseous as well as the dissolved concentration of N2O. Furthermore, the gas flow rate from each reactor was measured and the gas flux was estimated. The results confirmed that the anoxic reactor represents the main source of nitrous oxide production. A significant production of N2O was, however, also found in the anaerobic reactor, thus indicating a probable occurrence of the denitrifying phosphate accumulating organism activity. The highest N2O fluxes were emitted from the aerated reactors (3.09 g N2ON m-2 h-1 and 9.87 g N2ON m-2 h-1, aerobic and MBR tank, respectively). The emission factor highlighted that only 1% of the total treated nitrogen was emitted from the pilot plant. Furthermore, the measured N2O concentrations in the permeate flow were comparable with other reactors. Nitrous oxide mass balances outlined a moderate production also in the MBR reactor despite the low hydraulic retention time. On the other hand, the mass balance showed that in the aerobic reactor a constant consumption of nitrous oxide (up to almost 15 mg N2O h-1) took place, due to the high amount of stripped gas.
Asunto(s)
Reactores Biológicos , Óxido Nitroso/análisis , Eliminación de Residuos Líquidos/instrumentación , Desnitrificación , Gases/análisis , Nitrógeno/análisis , Nitrógeno/metabolismo , Óxido Nitroso/metabolismo , Fósforo/aislamiento & purificación , Proyectos Piloto , Aguas del Alcantarillado , Eliminación de Residuos Líquidos/métodosRESUMEN
A hybrid activated sludge/biofilm process was investigated for wastewater treatment in a cold climate region. This process, which contains both suspended biomass and biofilm, usually referred as IFAS process, is created by introducing plastic elements as biofilm carrier media into a conventional activated sludge reactor. In the present study, a hybrid process, composed of an activated sludge and a moving bed biofilm reactor was used. The aim of this paper has been to investigate the performances of a hybrid process, and in particular to gain insight the nitrification process, when operated at relatively low MLSS SRT and low temperatures. The results of a pilot-scale study carried out at the Department of Hydraulic and Environmental Engineering at the Norwegian University of Science and Technology in Trondheim are presented. The experimental campaign was divided into two periods. The pilot plant was first operated with a constant HRT of 4.5 hours, while in the second period the influent flow was increased so that HRT was 3.5 hours. The average temperature was near 11.5°C in the overall experimental campaign. The average mixed liquor SRT was 5.7 days. Batch tests on both carriers and suspended biomass were performed in order to evaluate the nitrification rate of the two different biomasses. The results demonstrated that this kind of reactor can efficiently be used for the upgrading of conventional activated sludge plant for achieving year-round nitrification, also in presence of low temperatures, and without the need of additional volumes.
Asunto(s)
Clima Frío , Aguas del Alcantarillado/química , Eliminación de Residuos Líquidos/métodos , Biopelículas , Noruega , Proyectos Piloto , Compuestos de Amonio Cuaternario , Contaminantes Químicos del AguaRESUMEN
This paper describes the moving bed biofilm reactor (MBBR) and presents applications of wastewater treatment processes in which this reactor is used. The MBBR processes have been extensively used for BOD/COD-removal, as well as for nitrification and denitrification in municipal and industrial wastewater treatment. This paper focuses on the municipal applications. The most frequent process combinations are presented and discussed. Basic design data obtained through research, as well as data from practical operation of various plants, are presented. It is demonstrated that the MBBR may be used in an extremely compact high-rate process (<1 h total HRT) for secondary treatment. Most European plants require P-removal and performance data from plants combining MBBR and chemical precipitation is presented. Likewise, data from plants in Italy and Switzerland that are implementing nitrification in addition to secondary treatment are presented. The results from three Norwegian plants that are using the so-called combined denitrification MBBR process are discussed. Nitrification rates as high as 1.2 g NH4-N/m2 d at complete nitrification were demonstrated in practical operation at low temperatures (11 degrees C), while denitrification rates were as high as 3.5g NO3-Nequiv./m2.d. Depending on the extent of pretreatment, the total HRT of the MBBR for N-removal will be in the range of 3 to 5 h.
Asunto(s)
Biopelículas , Reactores Biológicos , Purificación del Agua , Biopelículas/crecimiento & desarrollo , Biomasa , Reactores Biológicos/microbiología , Diseño de Equipo , Arquitectura y Construcción de Instituciones de Salud , Purificación del Agua/instrumentación , Purificación del Agua/métodosRESUMEN
The joint effect of wastewater salinity and hydrocarbons on nitrous oxide emission was investigated. The membrane bioreactor pilot plant was operated with two phases: i. biomass acclimation by increasing salinity from 10gNaClL(-1) to 20gNaClL(-1) (Phase I); ii. hydrocarbons dosing at 20mgL(-1) with a constant salt concentration of 20gNaClL(-1) (Phase II). The Phase I revealed a relationship between nitrous oxide emissions and salinity. During the end of the Phase I, the activity of nitrifiers started to recover, indicating a partial acclimatization. During the Phase II, the hydrocarbon shock induced a temporary inhibition of the biomass with the suppression of nitrous oxide emissions. The results revealed that the oxic tank was the major source of nitrous oxide emission, likely due to the gas stripping by aeration. The joint effect of salinity and hydrocarbons was found to be crucial for the production of nitrous oxide.
Asunto(s)
Reactores Biológicos , Hidrocarburos/metabolismo , Óxido Nitroso/análisis , Salinidad , Eliminación de Residuos Líquidos/métodos , Aguas Residuales/química , Biodegradación Ambiental , Biomasa , Cloruro de Sodio/metabolismo , Contaminantes Químicos del Agua/análisis , Contaminantes Químicos del Agua/química , Contaminantes Químicos del Agua/metabolismoRESUMEN
The continuously operated laboratory scale Kaldnes moving bed biofilm reactor (MBBR) was used for thermophilic (55 degrees C) aerobic treatment of TMP whitewater. In the MBBR, the biomass is grown on carrier elements that move along with the water in the reactor. Inoculation with mesophilic activated sludge gave 60-65% SCOD removal from the first day onwards. During the 107 days of experiment, the 60-65% SCOD removals were achieved at organic loading rates of 2.5-3.5 kg SCODm(-3) d(-1), the highest loading rates applied during the run and HRT of 13-22h. Carbohydrates, which contributed to 50-60% of the influent SCOD. were removed by 90-95%, while less than 15% of the lignin-like material (30-35% of SCODin) was removed. The sludge yield was 0.23g VSSg SCOD(-1)removed. The results show that the aerobic biofilm process can be successfully operated under thermophilic conditions.