Effect of basic and basic/acid modifications on the surface of PVDF membranes for the insertion of TiO2 and its use in environmental applications.

Supporting titanium oxide (TiO2) on polymeric membrane surfaces is a strategy to increase the photocatalytic activity of this material as well as to modify membrane surface with antifouling properties or to develop hybrid processes of water treatment. The chemical characteristics of the polymeric membrane surfaces are a determining factor in the correct impregnation of TiO2 particles. In this work, the titanium oxide was immobilized on polyvinylidene fluoride (PVDF) membrane surface by direct impregnation during the synthesis of the inorganic particles by sol-gel route. The PVDF membranes were previously modified by treatments based on an alkaline attack followed by acid treatment. The final TiO2-modified membranes were characterized by infrared and Raman spectroscopy, as well as by scanning electron microscopy. In addition, the changes on the surface characteristics were determined by contact angle measurements. Finally, the membranes were tested on the photocatalytic degradation of methyl orange (MO). The results obtained indicate that the basic/acid pretreatment allows the generation of active sites in the membrane and that when carrying out the synthesis of TiO2 on the membrane, it can be anchored stably on its surface and through the pores. The microscopies indicate that the structure of the membrane is not compromised by the pretreatment. The amount of TiO2 deposited on the membrane was of 0.1580 ± 0.01773 mg TiO2/cm2 membrane. With this amount of TiO2, a degradation percentage of 98.2% is achieved after 450 min; when the membrane is used for a second cycle, a degradation percentage of 82.0% is obtained, which remains constant for 3 subsequent cycles. This method, which uses the PVDF membrane as a support for TiO2 particles, represents a low-cost and easy-to-prepare insertion procedure, with good degradation percentages, which means that the membrane can be used for subsequent studies in filtration systems in the treatment of effluents from the textile industry.

Thermal, morphological and structural characterization of a copolymer of starch and polyethylene.

The objective of this paper was to perform a copolymerization between polyethylene and starch in order to obtain new environmentally friendly materials. The copolymer obtained was characterized thermally, morphologically and structurally, including its pasting profile. The starch-g-PE copolymer showed lower thermal stability compared to the control materials. FTIR analysis determined that the chemical bond signal between the starch and polyethylene in the copolymer overlaps with the native starch signals. The signal from this chemical bond was assigned by proton NMR spectroscopy at δ 4.45 ppm. X-ray studies of the copolymer showed a material with more amorphous characteristics compared to native starch. SEM analysis demonstrated the presence of cracks in the starch granules which favored the chemical interaction between the polymers. The pasting behavior of the copolymer was less pronounced compared to native starch. Therefore, the copolymerization of both polymers could be an alternative to recycle polyethylene and make biodegradable materials.