Evaluation of heavy metal contamination levels in river sediments and their risk to human health in urban areas: A case study in the Matanza-Riachuelo Basin, Argentina.

Anthropogenic contamination of Cd, Cr, Cu, Ni, Pb and Zn in riverbed sediments of the Pampean area (Matanza-Riachuelo Basin, MRB), Argentina, was evaluated using various indices: Geo-accumulation Index (Igeo), Contamination Factor (Cf), Metal Pollution Index (MPI), Pollution Load Index (PLI) and Contamination Degree (Cdeg). A database based on previous samplings of heavy metal concentrations at different sites in the Upper, Middle and Lower MRB was used. The Igeo and Cf values are calculated using selected local background (Pristine Pampean loess, LZB), and global average shale values (ASTW). Paired Igeo and Cf results with LZB and ASTW fall in dissimilar classes, especially in respect of Cd. In turn, MPI, PLI and Cdeg show similar results, as they do not have the same degree of confidence as Igeo and Cf. The Upper Basin, mainly rural, shows the following profile of sediment contamination: Cd > Ni > Cu â‰« Pb > Zn > Cr. The Middle Basin, which is at the periphery of a very industrialised and urban area, displays the following contamination profile for both Igeo and Cf: Cu > Pb > Zn > Ni > Cd > Cr. Conversely, in the Lower Basin, where land-use is urban/industrial, the levels of metal contamination are higher and appear in this order: Cr > Pb > Cu > Zn > Ni > Cd. Cadmium, Cu, Ni and Zn have shown no significant oral and/or dermal HQ nor carcinogenic risk but the potential risk posed by Cr and Pb must be taken into account. Maximum and mean values of Cr total carcinogenic risk (TCR) as well as Ni TCR also point to a health risk to children in the Lower Basin Area. All the data analysed confirm that industrial and urban growth without land-use planning, and a poor environmental legislation until the beginning of the 21st century, have not provided the necessary framework for sustainable development in the MRB.

Assessment of toxic metal contamination using a regional lithogenic geochemical background, Pampean area river basin, Argentina.

Contamination assessment in riverbed sediments depends on the accurate determination of the background values. The aim of this study is to assess the degree of contamination and to evaluate the most adequate background for the determination of anthropogenic contamination in Cd, Cr, Cu, Ni, Pb and Zn in bed sediments of the Pampean area river basin (Matanza-Riachuelo River and tributary streams), Argentina. The geo-accumulation index (Igeo) values were calculated using selected lithogenic backgrounds (loess, loessoid sediments and paleosoils), the metal concentrations in the residual fraction (F4) in riverbed sediments and a global average shale often applied in the estimation of toxic metal Igeo. The IgeoF4, IgeoLZB and most of the others Igeos, indicated that in land areas used mainly for agriculture and cattle grazing, the superficial sediments were uncontaminated with Cd, Cr, Cu and Zn, and slightly contaminated with Ni and Pb. Conversely, in those areas dedicated to urban and industrial use, the metal contamination was greater. Overall, the relatively significant anthropogenic contamination of Cr > Pb ≥ Cu > Zn > Ni > Cd in the Riachuelo River area was associated with metallurgic activities, tanning and industrial waste. The comparative analysis of different values suggested that Buenos Aires' "pristine" loess could be recommended to evaluate the Igeo index of riverbed sediments in the Pampean area. To enhance the use of the selected background, the normalized enrichment factor using Al. In this study case, the Igeo and the EF using LZB background display the same trend, showing the greatest degree of contamination, as would be expected, in Riachuelo samples (RIA 1 and RIA 2) located in the urban/industrial area.