Iodo-Functionalized Salicylideneimine-Boron Complexes: Synthesis and Photosensitized Degradation of Organic Water Pollutants.

Boron-containing organic compounds are reported to have excellent luminescent properties, however, their ability to photosensitize singlet oxygen generation remains unexplored. The synthesis of several Schiff-base based boranils is reported, starting from commercially available salicylaldehydes and anilines. The iodo-functionalized derivatives were observed to aid in the photosensitized generation of singlet oxygen. Poly(methylmethacrylate) films incorporating these molecules were prepared and were demonstrated to be capable of serving as a reusable heterogeneous medium for the photosensitized degradation of organic water pollutants.

Multifunctional BODIPY embedded non-woven fabric for CO release and singlet oxygen generation.

Materials that can simultaneously release CO and generate singlet oxygen upon visible light irradiation under ambient conditions are highly desirable for therapeutic applications. Furthermore, materials that can sequester the undesirable side products into the matrix without affecting the release of CO and singlet oxygen generation would allow them to be used for practical applications. Focussing on these aspects, we prepared two dipicolylamine appended BODIPY­manganese(I) tricarbonyl complexes wherein the metal core was systematically tethered at 5- and 8- positions of the BODIPY core. The complexes were embedded into a polymer matrix via electrospinning and the resulting non-woven fabrics showed CO release as well as singlet oxygen generation upon irradiation. While the hybrid materials were non-toxic in dark, they were strongly photocytotoxic to c6 cancer cells when exposed to light. Rapid CO release alongside significant singlet oxygen generation, indefinite dark stability, good biocompatibility and negligible dark toxicity makes these fabrics a potent candidate for phototherapeutic applications.

A visible-light activated ROS generator multilayer film for antibacterial coatings.

The current scenario of antibiotic-resistant bacteria and pandemics caused by viruses makes research in the area of antibacterial and antiviral materials and surfaces more urgent than ever. In this regard, salicylideneimine based tetracoordinate boron-containing organic compounds are emerging as a new class of photosensitizers for singlet oxygen generation. However, the inherent inability of small organic molecules to be processed limits their potential use in functional coatings. Here we show the synthesis of a novel polymer functionalized with diiodosalicylideneimine-boron difluoride (PEI-BF2) and its utility for surface coating inside glass vials via layer-by-layer (LbL) assembly. The multilayer thin films are characterized using AFM and UV-Vis spectroscopy and the resultant coatings display excellent stability. The multilayer coating could be activated using visible light, and owing to the photocatalytic activity of the incorporated PEI-BF2, the surface coating is able to generate singlet oxygen efficiently upon light irradiation. Further, the multilayer coated surfaces exhibit remarkable antimicrobial activity towards both Gram-positive and Gram-negative bacteria under a variety of conditions. Thus, owing to the simple synthesis and the convenient methodology adopted for the preparation of multilayer coatings, the material reported here could pave the way for the development of sunlight activated large area self-sterile surfaces.

Advances in the Supramolecular Chemistry of Tetracoordinate Boron-Containing Organic Molecules into Organogels and Mesogens.

Boron-containing organic compounds are well accepted as a class of compounds having excellent photophysical properties. In addition to the unique photophysical properties, the ease of synthesis and structural robustness make tetracoordinate boron complexes ideal for a variety of applications. While significant light has been thrown on their luminescence properties, there is no collective attention to their supramolecular chemistry. In this mini review, we discuss the progress made in the supramolecular chemistry of these compounds which includes their utility as building blocks for liquid crystalline materials and gels largely driven by various non-covalent interactions like H-bonding, CH-π interactions, BF-π interactions and Van der Waals forces. The organoboron compounds presented here are prepared from easy-to-synthesize chelating units such as imines, diiminates, ketoiminates and diketonates. Moreover, the presence of heteroatoms such as nitrogen, oxygen and sulfur, and the presence of aromatic rings facilitate non-covalent interactions which not only favor their formation but also helps to stabilize the self-assembled structures.