1.
J Org Chem
; 89(1): 474-483, 2024 Jan 05.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38096480
RESUMEN
A radical 1,2,4-trifunctional reaction of thiosulfonate to unactivated olefin is achieved by a migration strategy under mild conditions. In this reaction, the more unstable primary free radicals are in situ generated after the migration of heteroaryl groups in the presence of DABCO. This trifunctionalization of unactivated olefins involves two C-S bond formations and one C-C bond formation.