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A "hotspot"-rich Ag-nanoparticle-decorated three-dimensional polymer substrate was fabricated, exhibiting an excellent surface-enhanced Raman scattering (SERS) activity. 4-Mercaptobenzoic acid (MBA) was selected as a probe molecule for comparing the SERS activity on selected substrates. The proposed detection chip with the adsorption of tetramethylthiuram disulfide (TTD) shows an excellent sensitivity for the quantitative determination of TTD and mercury ions (Hg2+). This chip exhibited a high sensitivity for the trace detection of the targets. Interestingly, we found that the adsorbed TTD is selectively sensitive to Hg2+. The SERS band had a significant frequency shift of 11 cm-1 as the concentration of Hg2+ increased from 10-10 to 10-3 mol L-1. More importantly, the frequency shift of the SERS band exhibited an excellent linear relationship with the concentration of Hg2+, and the determination limit for Hg2+ was 10-10 mol L-1. Furthermore, the proposed detection chip shows great application potential for the determination of pesticides and Hg2+.
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Mercurio , Nanopartículas del Metal , Polímeros , Espectrometría Raman , TiramRESUMEN
Concentrations of selected heavy metals (Cd, Cr, Cu, Pb, Ni, Fe, and Zn), nutrients (NO (3) (-) and NH(3)), fecal coliform colonies, and other multiple physical-chemical parameters were measured seasonally from 12 locations in an urban New Jersey estuary between 1994 and 2008. Stepwise regression, principal component analysis, and cluster analysis were used to group water quality results and sampling locations, as well as to assess these data's relationship to sewage treatment effluents and the distance to the mouth of the river. The BOD(5), NH(3), NO (3) (-) and fecal coliform counts clustered as one group and positively correlated to the distances from treated effluent and the measures of magnitude at the discharge points. Dissolved solids and most metal species scored high along a single principal component axes and were significantly correlated with the proximity to the industrialized area. From these data, one can conclude that the effluent discharge has been a main source of anthropogenic input to the Hackensack River over the past 15 years. Therefore, the greatest improvement to water quality would come from eliminating the few remaining combined sewer overflows and improving the removal of nutrients from treated effluents before they are discharged into the creeks and river.
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Monitoreo del Ambiente , Estuarios , Agua Dulce/química , Contaminantes Químicos del Agua/análisis , Contaminación Química del Agua/estadística & datos numéricos , Ciudades , Humanos , Concentración de Iones de Hidrógeno , Metales/análisis , Análisis Multivariante , New Jersey , Salinidad , Urbanización , Microbiología del AguaRESUMEN
Synthetic chemical fertilizers are a fundamental source of nutrition for agricultural crops; however, their limited availability, low plant uptake, and excessive application have caused severe ecological imbalances. In addition, the gravity of environmental stresses, such as salinity and water stress, has already exceeded the threshold limit. Therefore, the optimization of nutrient efficiency in terms of plant uptake is crucial for sustainable agricultural production. To address these challenges, we isolated the rhizospheric fungus Curvularia lunata ARJ2020 (AR11) and screened the optimum doses of biochar, silicon, and potassium phosphate (K2HPO4), and used them-individually or jointly-to treat rice plants subjected to salt (150 mM) and drought stress (20-40% soil moisture). Bioassay analysis revealed that AR11 is a highly halotolerant and drought-resistant strain with an innate ability to produce gibberellin (GA1, GA3, GA4, and GA7) and organic acids (i.e., acetic, succinic, tartaric, and malic acids). In the plant experiment, the co-application of AR11 + Biochar + Si + K2HPO4 significantly improved rice growth under both salt and drought stresses. The plant growth regulator known as abscisic acid, was significantly reduced in co-application-treated rice plants exposed to both drought and salt stress conditions. These plants showed higher Si (80%), P (69%), and K (85%) contents and a markedly low Na+ ion (208%) concentration. The results were further validated by the higher expression of the Si-carrying gene OsLSi1, the salt-tolerant gene OsHKT2, and the OsGRAS23's drought-tolerant transcriptome. Interestingly, the beneficial effect of AR11 was significantly higher than that of the co-application of Biochar + Si + K2HPO4 under drought. Moreover, the proline content of AR11-treated plants decreased significantly, and an enhancement of plant growth-promoting characteristics was observed. These results suggest that the integrated co-application of biochar, chemical fertilizers, and microbiome could mitigate abiotic stresses, stimulate the bioavailability of essential nutrients, relieve phytotoxicity, and ultimately enhance plant growth.
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The bullying experiences of Korean-American adolescents (N = 295) were explored in relation to discrimination and mental health outcomes. Bullying experiences were assessed by the Bully Survey (Swearer, 2005), discrimination by the Perceived Ethnic and Racial Discrimination Scale (Way, 1997) and depression by the Center for Epidemiological Studies - Depression Scale (CES-D). Those who reported being bullied (31.5%) as well as those who reported both being bullied and bullying others (15.9%) experienced a higher level of depression, which was elevated beyond the clinically significant level of CES-D. The results of a LISREL model suggest that the experiences of bullying among Korean/Asian-American adolescents and their related mental health issues need to be addressed in a comprehensive context of their discrimination experiences, acculturation, family and school environments.
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Conducta del Adolescente/etnología , Asiático/psicología , Acoso Escolar/psicología , Prejuicio , Adolescente , Depresión , Femenino , Humanos , Masculino , New Jersey , New York , República de Corea/etnología , Encuestas y Cuestionarios , Adulto JovenRESUMEN
BACKGROUND: The study examined whether Vietnamese mothers of children with cognitive delay experienced more parenting stress compared to mothers of children without delay, and the factors that contribute to the parenting stress. METHOD: The study sample included 225 mothers of children with and without cognitive delays from Hue City in Vietnam. The study protocol included mothers reporting on the scales of parenting stress and perceived social support, and on demographic questions. RESULTS: Mothers of children with cognitive delay experienced more stress. They were poorer and less educated, and perceived less social support. More mothers of these children had health issues. Having a child with cognitive delay was the strongest predictor of stress after controlling other demographic and psychosocial variables. CONCLUSION: Special education and early intervention services should be developed and available to educate the children with cognitive delay and support their mothers in Vietnam. Effective services also need to address their poverty and health care needs.
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Niños con Discapacidad/estadística & datos numéricos , Discapacidad Intelectual/epidemiología , Responsabilidad Parental/psicología , Estrés Psicológico/epidemiología , Estrés Psicológico/psicología , Adulto , Niño , Preescolar , Femenino , Humanos , Masculino , Persona de Mediana Edad , Valor Predictivo de las Pruebas , Prevalencia , Estudios Prospectivos , Estrés Psicológico/diagnóstico , Encuestas y Cuestionarios , Vietnam/epidemiología , Adulto JovenRESUMEN
Parents of young children with disabilities experience increased parenting stress owing to the caregiving demands the children place on them and concern over how they will raise and care for their children in the future. Support or understanding from others can be helpful in relieving the psychological and physical strain that caregivers experience. The project examined the types and availability of social support for Vietnamese parents of young children with cognitive delays, and their perceived social support and parenting stress. Fourteen types of informal support (spouse, wife's father, wife's mother, husband's father, husband's mother, wife's siblings, husband's siblings, sons, daughters, other relatives, friends, neighbors, and parents of other children with disabilities and social helpers) and eight types of professional support (teachers, therapists, doctors, private therapists, home helpers, social agencies, babysitters, and doctors in community health clinics) were available. When the level of intellectual functioning among children was lower, both mothers and fathers reported less availability of support from most types of informal support and teachers. For both mothers and fathers, a larger network of informal and professional support reduced the amount of stress they experienced. Specifically, however, when immediate family members were not available, mothers were more likely to experience parenting stress whereas the unavailability of friends and neighbors increased fathers' parenting stress. While addressing the stigma in society that affects the lives of the families of the children with disabilities in gaining informal support, the need for developing professional services in developing countries is discussed.
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Cuidadores/psicología , Trastornos del Conocimiento , Familia/psicología , Accesibilidad a los Servicios de Salud/estadística & datos numéricos , Responsabilidad Parental/psicología , Apoyo Social , Estrés Psicológico/etiología , Adulto , Niño , Preescolar , Femenino , Necesidades y Demandas de Servicios de Salud , Humanos , Masculino , Persona de Mediana Edad , Clase Social , Estrés Psicológico/terapia , VietnamRESUMEN
OBJECTIVES: The project assessed the efficacy of a home-based intervention program for young children (n= 64, ages ranging from 3-6 years) with developmental delays in Vietnam. It was hypothesized that the children in the intervention group would show greater progress in adaptive behavior than the children in the control group. METHODS: Assessment of the program efficacy was carried out by comparing children who received services for 6 months and those who did not. Children who were recognized as having developmental delays by teachers in kindergarten programs, and confirmed by trained evaluators based on the Vineland Adaptive Behavior Scale-II (VABS-II), were randomly assigned to intervention and control groups. Twenty student teachers were recruited from a teaching university and were provided with pre-program training and ongoing supervision. RESULTS: The outcomes of the program were examined at 0, 3, and 6 months using the VABS-II. The intervention group improved significantly more than the control group in overall adaptive functioning and in the areas of communication, social skills and motor skills. CONCLUSION: The project is one of only a few early intervention projects to apply randomized control trials in a low-middle-income country. The results demonstrate the feasibility of carrying out the intervention program using teachers with no prior experience of working with children with delays/disabilities, where professional resources are scarce for this population.
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Atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) and its degradation products are important contaminants of world water systems and have effects on aquatic life. These effects are modulated by the degradation of atrazine, which depends, in part, on its reactivity with soil minerals. We have studied the degradation reaction of atrazine on synthetic birnessite (delta-MnO2) in the aqueous phase using a batch reactor and a developed high-performance liquid chromatography method. The reaction was studied in the absence of light at 25 degrees C and between pH 2.3 to pH 8.3. The reaction rates increased with decreasing pH and increasing delta-MnO2 loading, and they did not follow simple first-order kinetics. The major products are hydroxylated and mono- and didealkylatrazine. Ammeline and cyanuric acid also were detected. The half-life (t 1/2) for the degradation of atrazine was approximately 16.8 d and independent of oxygen. Manganese(II) evolution was a minor product. The mechanism of dealkylation involved proton transfer to Mn(IV)-stabilized oxo and imido bonds, with no net oxidation and reduction. Oxidation was a secondary reaction. The proposed abiotic pathway for the transformation of atrazine on delta-MnO2 was identical to the reported biotic pathway. Thus, delta-MnO2, a common soil component, facilitated the efficient N-dealkylation and hydrolysis of the herbicide atrazine at 25 degrees C, possibly via a nonoxidative mechanisms. The N-dealkylation has been attributed strictly to a biological process in soils.
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Atrazina/química , Herbicidas/química , Óxidos/química , Atrazina/análisis , Cromatografía Líquida de Alta Presión , Remoción de Radical Alquila , Semivida , Herbicidas/análisis , Concentración de Iones de Hidrógeno , Hidrólisis , Compuestos de Manganeso/química , Oxidación-Reducción , Agua/químicaRESUMEN
INTRODUCTION: Intellectual disabilities are as prevalent in East Asian countries as in the West (0.06%-1.3%). Widespread discrimination against intellectual disabilities in Asia may initiate stigma that places unfair restrictions on the social life of these individuals and their caregivers. We utilised established stigma frameworks to assess the extent to which a child's intellectual disability contributes to the social exclusion of caregivers in Vietnam. METHODS: A mixed quantitative and qualitative approach was employed to examine the experience of social life restriction among parents of children with intellectual disabilities. The child's disability level and restrictions on caregivers' social experiences were assessed among 70 mothers and fathers recruited from schools in Hue City, Vietnam. Qualitative responses describing social exclusion were also recorded. RESULTS: Caregivers reported elevated levels of social exclusion. As hypothesised, parents of children with greater intellectual disability experienced more restrictions on their social life (Beta = 0.79, 95% confidence interval 0.27-1.30, standard error = 0.26, p < 0.01). Qualitative analyses indicated that the threatening of core cultural norms (inability to be employed or married upsets community harmony) initiated labelling, social exclusion and efforts to keep the condition secret or withdraw from others. CONCLUSION: This study is among the first to demonstrate the impacts of intellectual disabilities on caregivers' social functioning in Asia. The findings illustrate how traditional Asian norms initiate stigma, which in turn restricts key social interactions among caregivers. Psycho-educational interventions may address the social domains in which caregivers are impacted and encourage sustained help-seeking among caregivers for their children.
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Discapacidad Intelectual/psicología , Discapacidad Intelectual/terapia , Estigma Social , Actitud Frente a la Salud , Cuidadores , Niño , Preescolar , Niños con Discapacidad , Femenino , Humanos , Masculino , Padres , Ajuste Social , Conducta Social , Apoyo Social , Estrés Psicológico , Encuestas y Cuestionarios , VietnamRESUMEN
This study was conducted to examine an adaptation of the Vineland Adaptive Behavior Scale (VABS) [Sparrow, S. S., Balla, D. A., & Cicchetti, D. V. (1984). The Vineland Adaptive Behavior Scales. Circle Pines, MN: America Guidance Service; Sparrow, S. S., Balla, D. A., & Cicchetti, D. V. (2005). Vineland Adaptive Behavior Scales Second Edition Survey Forms Manual. AGS Publishing] and its psychometric properties in Vietnamese culture. The 1984 version of VABS was translated and adapted to form the Vietnamese version of the Vineland Adaptive Behavior Scales (VVABS). The scale was administered to 120 Vietnamese mothers of non-disabled preschool-age children enrolled in kindergarten programs. It was found that the VVABS has acceptable levels of internal consistency reliability and construct validity, and could discriminate successfully between Vietnamese children with intellectual disabilities from those of typical development. The results that were comparable to the VABS indicate a successful adaptation of the construct and measure of adaptive behavior to a non-western culture.
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Adaptación Psicológica , Pruebas Neuropsicológicas/estadística & datos numéricos , Actividades Cotidianas , Niño , Preescolar , Comunicación , Comparación Transcultural , Análisis Discriminante , Familia , Humanos , Reproducibilidad de los Resultados , Instituciones Académicas , Población Urbana , VietnamRESUMEN
The informal and professional supports available for families of children with mental retardation in Korea and the United States were examined and the effects of culture and social support on maternal stress considered. Thirty-eight American and 40 Korean mothers participated in the home-visit interview. A pilot study identified 10 types of informal and 11 types of professional support for the two national groups. Results showed that American mothers received more informal and professional support in almost all domains of social support; Korean mothers experienced more stress. Possible explanations for these differences were explored.