RESUMEN
The asymmetric unit of the title compound, C18H17N3O, consists of two independent mol-ecules, each having an E conformation with respect to the C=C bond between the benzodiazepinone and di-methyl-amine groups. In the crystal, the two independent mol-ecules are linked into a dimer by a pair of N-Hâ¯O hydrogen bonds.
RESUMEN
The title compound, C21H19N3O, exhibits an E configuration with respect to the C=C bond between the benzodiazepine and tri-methyl-amine groups. The seven-membered diazepine ring displays a boat conformation. In the crystal, mol-ecules are linked by a C-Hâ¯O hydrogen bond, forming a chain along [110].
RESUMEN
In the title compound, C13H18O3, the benzene ring is almost perpendicular to the acet-oxy plane, making a dihedral angle of 89.33â (11)°. In the crystal, mol-ecules are linked by weak C-Hâ¯O hydrogen bonds, forming a zigzag chain along the c-axis direction.
RESUMEN
In the title compound, C(27)H(23)Cl(3)N(4)O(2), the seven-membered diazepine ring adopts a boat conformation. The triazole ring makes dihedral angles of 17.24â (8) and 82.86â (8)°, respectively, with the chloro-benzene ring and the benzene ring of the benzodiazepine unit.
RESUMEN
There are two independent mol-ecules in the asymmetric unit of the title compound {systematic name: ethyl 2-(2-methyl-1H-benzimidazol-1-yl)-2-[2-(4-nitro-phen-yl)hydrazinyl-idene]ethano-ate}, C(18)H(17)N(5)O(4). Each mol-ecule and its inversion-related partner are linked by a pair of inter-molecular N-Hâ¯N hydrogen bonds, forming inversion dimers in the crystal structure.
RESUMEN
The complete mol-ecule of the title compound, C(20)H(18)N(6)O(8), is generated by a crystallographic twofold axis. The dihedral angle between the nitrobenzene rings is 43.5â (2)°. The central six-membered ring exhibits a boat conformation. In the crystal structure, weak inter-molecular C-Hâ¯O inter-actions are observed.