Fifteen-year global time series of satellite-derived fine particulate matter.

Ambient fine particulate matter (PM2.5) is a leading environmental risk factor for premature mortality. We use aerosol optical depth (AOD) retrieved from two satellite instruments, MISR and SeaWiFS, to produce a unified 15-year global time series (1998-2012) of ground-level PM2.5 concentration at a resolution of 1° x 1°. The GEOS-Chem chemical transport model (CTM) is used to relate each individual AOD retrieval to ground-level PM2.5. Four broad areas showing significant, spatially coherent, annual trends are examined in detail: the Eastern U.S. (-0.39 ± 0.10 µg m(-3) yr(-1)), the Arabian Peninsula (0.81 ± 0.21 µg m(-3) yr(-1)), South Asia (0.93 ± 0.22 µg m(-3) yr(-1)) and East Asia (0.79 ± 0.27 µg m(-3) yr(-1)). Over the period of dense in situ observation (1999-2012), the linear tendency for the Eastern U.S. (-0.37 ± 0.13 µg m(-3) yr(-1)) agrees well with that from in situ measurements (-0.38 ± 0.06 µg m(-3) yr(-1)). A GEOS-Chem simulation reveals that secondary inorganic aerosols largely explain the observed PM2.5 trend over the Eastern U.S., South Asia, and East Asia, while mineral dust largely explains the observed trend over the Arabian Peninsula.

Ozone sensitivity analysis with the MM5-CMAQ modeling system for Shanghai.

Ozone has become one of the most important air pollution issues around the world. This article applied both O3/(NO(y)-NO(x)) and H2O2/HNO3 indicators to analyze the ozone sensitivity in urban and rural areas of Shanghai, with implementation of the MM5-CMAQ modeling system in July, 2007. The meteorological parameters were obtained by using the MM5 model. A regional emission inventory with spatial and temporal allocation based on the statistical data has been developed to provide input emission data to the MM5-CMAQ modeling system. Results showed that the ozone concentrations in Shanghai show clear regional differences. The ozone concentration in rural areas was much higher than that in the urban area. Two indicators showed that ozone was more sensitive to VOCs in urban areas, while it tended to be NO(x) sensitive in rural areas of Shanghai.

Estimating mercury emissions from a zinc smelter in relation to China's mercury control policies.

Mercury concentrations of flue gas at inlet/outlet of the flue gas cleaning, electrostatic demister, reclaiming tower, acid plant, and mercury contents in zinc concentrate and by-products were measured in a hydrometallurgical zinc smelter. The removal efficiency of flue gas cleaning, electrostatic demister, mercury reclaiming and acid plant was about 17.4%, 30.3%, 87.9% and 97.4% respectively. Flue gas cleaning and electrostatic demister captured 11.7% and 25.3% of the mercury in the zinc concentrate, respectively. The mercury reclaiming tower captured 58.3% of the mercury in the zinc concentrate. About 4.2% of the mercury in the zinc concentrate was captured by the acid plant. Consequently, only 0.8% of the mercury in the zinc concentrate was emitted to the atmosphere. The atmospheric mercury emission factor was 0.5 g t(-1) of zinc produced for the tested smelter, indicating that this process offers the potential to effectively reduce mercury emissions from zinc smelting.

Efficient regional ozone control strategies for the eastern United States.

When environmental regulatory bodies formulate control plans, it is incumbent upon them to try to achieve the stated goals in an economically efficient manner. The US Environmental Protection Agency (EPA) is presently developing regulations to limit the influence of transported ozone on areas that are having difficulty meeting the ambient air quality standard. EPA has proposed stringent control measures for emissions of nitrogen oxides (NOx) in 22 states of the eastern US. The strategy would necessitate the use of selective catalytic reduction or similar high-performance technology on almost all major power plants in the region, as well as extensive controls on industrial sources. This paper suggests several alternative approaches that would achieve equal or better environmental improvement at lower cost. These include focusing control efforts on sources closer to the North-east Corridor, pushing controls on close-in sources to a higher level of technology performance, and relaxing the stringency of requirements for states remote from ozone problem areas. All the approaches examined are two to three times more cost-effective than EPA's proposed approach in the North-east Corridor.