1.
J Org Chem
; 88(7): 4528-4535, 2023 Apr 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36913662
RESUMEN
A copper-catalyzed cascade multicomponent reaction for synthesizing ditriazolyl diselenides from azides, terminal alkynes, and elemental selenium has been developed. The present reaction features utilizing readily available and stable reagents, high atom-economy, and mild reaction conditions. A possible mechanism is proposed.
2.
Org Lett
; 25(3): 517-521, 2023 Jan 27.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36649602
RESUMEN
An oxidative dehydrogenative coupling of thiols with alkanes via direct C(sp3)-H bond functionalization to form a new C-S bond and SâO double bond was developed. The present reaction features the use of readily available reagents and high step- and atom-efficiency, thus providing an efficient access to sulfoxides. A possible mechanism is proposed.