Facile synthesis of ZnO/CWO nanocomposite with brilliant enhanced optical response.

In this research, novel zinc oxide/cadmium tungstate (ZnO/CWO) nanocomposite was prepared by a simple chemical method. The prepared nanocomposite was characterized for its structural and optical properties by different techniques. For the first time, the radiation response of prepared nanocomposite was studied using 241Am alpha source and ion beam induced luminescence (IBIL) measurement. Also, photocurrent transient responses of the prepared nanocomposite were recorded under Xe source radiation. ZnO/CWO nanocomposite exhibited strong light emission in the blue-green range at room temperature. Under alpha irradiation, the ZnO/CWO nanocomposite showed an excellent sensitivity when compared to pure ZnO or CWO. FESEM and TEM images showed a uniform distribution of spherical nanoparticles with an average particle size of 77 nm. XRD, XPS, and EDX results indicated characteristic peaks of ZnO, CWO, and related elements in the composite. Fourier transform infrared spectroscopy confirmed the presence of several groups in the nanocomposite. Investigations indicated that the optical quality of the ZnO/CWO nanocomposite was improved when compared with pure ZnO and CWO. According to obtained results, it is anticipated that ZnO/CWO nanocomposite would hold suitable potential for applications in optoelectronic devices and detection.

Green synthesis of multifunctional ZnO/chitosan nanocomposite film using wild Mentha pulegium extract for packaging applications.

Following the global corona virus pandemic and environmental contamination caused by chemical plastic packaging, awareness of the need for environmentally friendly biofilms and antibacterial coatings is increasing. In this study, a biodegradable hybrid film, comprising of green-synthesized zinc oxide nanoparticles (ZnO NPs) with a chitosan (CS) matrix, was fabricated using a simple casting procedure. The ZnO NPs were synthesized using wild Mentha pulegium extract, and the synthesized NPs and films were characterized using different approaches. The structural, morphological, mechanical, antibacterial, and optical properties, as well as the hydrophilicity, of the prepared samples were investigated using various techniques. Gas chromatography-mass spectrometry measurements revealed the presence of phenolic compounds in the M. pulegium extract. In addition, a strong coordination connection between Zn2+ and the chitosan matrix was confirmed, which resulted in a good dispersion of ZnO in the chitosan film. The surface of the composite films was transparent, smooth, and uniform, and the flexible bio-based hybrid films exhibited significant antibacterial and antioxidant characteristics, strong visible emission in the 480 nm region, and UV-blocking properties. The ZnO/CS films displayed a potential to extend the shelf life of fruits by up to eight days when stored at 23°C, and also acted as an acceptable barrier against oxygen and water. The biodegradable ZnO/CS film is expected to keep fruit fresher than general chemical plastic films and be used for the packaging of active ingredients.