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Activated carbon derived from longan seeds in our laboratory and commercial activated carbon are used to investigate the adsorption of methane (CH4) and carbon dioxide (CO2). The adsorption capacity for activated carbon from longan seeds is greater than commercial activated carbon due to the greater BET area and micropore volume. Increasing the degree of burn-off can enhance the adsorption of CO2 at 273 K from 4 mmol/g to 4.2 and 4.8 mmol/g at 1000 mbar without burn-off, to 19 and 26% with burn-off, respectively. This is because an increase in the degree of burn-off increases the surface chemistry or concentration of functional groups. In the investigation of the effect of the hydroxyl group on the adsorption of CO2 and CH4 at 273 K, it is found that the maximum adsorption capacity of CO2 at 5000 mbar is about 6.4 and 8 mmol/g for cases without and with hydroxyl groups contained on the carbon surfaces. The opposite behavior can be observed in the case of methane, this is due to the stronger electrostatic interaction between the hydroxyl group and carbon dioxide. The simulation results obtained from a Monte Carlo simulation method can be used to support the mechanism in this investigation. Iron oxide is added on carbon surfaces with different concentrations to reveal the effects of ferric compounds on the adsorption of CO2. Iron at a concentration of about 1% on the surface can improve the adsorption capacity. However, excessive amounts of iron led to a limited adsorption capacity. The simulation result shows similar findings to the experimental data. The findings of this study will contribute to the progress of gas separation technologies, paving the way for long-term solutions to climate change and greenhouse gas emissions.
RESUMEN
A new and simple method, based entirely on a physical approach, was proposed to produce activated carbon from longan fruit seed with controlled mesoporosity. This method, referred to as the OTA, consisted of three consecutive steps of (1) air oxidation of initial microporous activated carbon of about 30% char burn-off to introduce oxygen surface functional groups, (2) the thermal destruction of the functional groups by heating the oxidized carbon in a nitrogen atmosphere at a high temperature to increase the surface reactivity due to increased surface defects by bond disruption, and (3) the final reactivation of the resulting carbon in carbon dioxide. The formation of mesopores was achieved through the enlargement of the original micropores after heat treatment via the CO2 gasification, and at the same time new micropores were also produced, resulting in a larger increase in the percentage of mesopore volume and the total specific surface area, in comparison with the production of activated carbon by the conventional two-step activation method using the same activation time and temperature. For the activation temperatures of 850 and 900 °C and the activation time of up to 240 min, it was found that the porous properties of activated carbon increased with the increase in activation time and temperature for both preparation methods. A maximum volume of mesopores of 0.474 cm3/g, which accounts for 44.1% of the total pore volume, and a maximum BET surface area of 1773 m2/g was achieved using three cycles of the OTA method at the activation temperature of 850 °C and 60 min activation time for each preparation cycle. The two-step activation method yielded activated carbon with a maximum mesopore volume of 0.270 cm3/g (33.0% of total pore volume) and surface area of 1499 m2/g when the activation temperature of 900 °C and a comparable activation time of 240 min were employed. Production of activated carbon by the OTA method is superior to the two-step activation method for better and more precise control of mesopore development.
Asunto(s)
Aire , Carbón Orgánico/química , Temperatura , Biomasa , Carbono/química , Dióxido de Carbono/química , Modelos Moleculares , Nitrógeno/química , Oxidación-Reducción , Porosidad , Semillas/química , Espectroscopía Infrarroja por Transformada de Fourier , Propiedades de Superficie , TermogravimetríaRESUMEN
Microporous- and mesoporous-activated carbons were produced from longan seed biomass through physical activation with CO2 under the same activation conditions of time and temperature. The specially prepared mesoporous carbon showed the maximum porous properties with the specific surface area of 1773 m2/g and mesopore volume of 0.474 cm3/g which accounts for 44.1% of the total pore volume. These activated carbons were utilized as porous adsorbents for the removal of methylene blue (MB) from an aqueous solution and their effectiveness was evaluated for both the adsorption kinetics and capacity. The adsorption kinetic data of MB were analyzed by the pseudo-first-order model, the pseudo-second-order model, and the pore-diffusion model equations. It was found that the adsorption kinetic behavior for all carbons tested was best described by the pseudo-second-order model. The effective pore diffusivity (De) derived from the pore-diffusion model had the values of 4.657 × 10-7-6.014 × 10-7 cm2/s and 4.668 × 10-7-19.920 × 10-7 cm2/s for the microporous- and mesoporous-activated carbons, respectively. Three well-known adsorption models, namely the Langmuir, Freundlich and Redlich-Peterson equations were tested with the experimental MB adsorption isotherms, and the results showed that the Redlich-Peterson model provided the overall best fitting of the isotherm data. In addition, the maximum capacity for MB adsorption of 1000 mg/g was achieved with the mesoporous carbon having the largest surface area and pore volume. The initial pH of MB solution had virtually no effect on the adsorption capacity and removal efficiency of the methylene blue dye. Increasing temperature over the range from 35 to 55 °C increased the adsorption of methylene blue, presumably caused by the increase in the diffusion rate of methylene blue to the adsorption sites that could promote the interaction frequency between the adsorbent surface and the adsorbate molecules. Overall, the high surface area mesoporous carbon was superior to the microporous carbon in view of the adsorption kinetics and capacity, when both carbons were used for the removal of MB from an aqueous solution.
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Biomasa , Carbón Orgánico/química , Azul de Metileno/química , Sapindaceae/química , Semillas/química , Contaminantes Químicos del Agua/química , Adsorción , Algoritmos , Cinética , Modelos Teóricos , Porosidad , Temperatura , Termodinámica , Purificación del AguaRESUMEN
Pore development and the formation of oxygen functional groups were studied for activated carbon prepared from bamboo (Bambusa bambos) using a two-step activation with CO2, as functions of carbonization temperature and activation conditions (time and temperature). Results show that activated carbon produced from bamboo contains mostly micropores in the pore size range of 0.65 to 1.4 nm. All porous properties of activated carbons increased with the increase in the activation temperature over the range from 850 to 950 °C, but decreased in the temperature range of 950 to 1000 °C, due principally to the merging of neighboring pores. The increase in the activation time also increased the porous properties linearly from 60 to 90 min, which then dropped from 90 to 120 min. It was found that the carbonization temperature played an important role in determining the number and distribution of active sites for CO2 gasification during the activation process. Empirical equations were proposed to conveniently predict all important porous properties of the prepared activated carbons in terms of carbonization temperature and activation conditions. Oxygen functional groups formed during the carbonization and activation steps of activated carbon synthesis and their contents were dependent on the preparation conditions employed. Using Boehm's titration technique, only phenolic and carboxylic groups were detected for the acid functional groups in both the chars and activated carbons in varying amounts. Empirical correlations were also developed to estimate the total contents of the acid and basic groups in activated carbons in terms of the carbonization temperature, activation time and temperature.
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Dióxido de Carbono , Carbón Orgánico , Adsorción , Nitrógeno/química , Porosidad , TemperaturaRESUMEN
Adsorption of carbon dioxide and methane in porous activated carbon and carbon nanotube was studied experimentally and by Grand Canonical Monte Carlo (GCMC) simulation. A gravimetric analyzer was used to obtain the experimental data, while in the simulation we used graphitic slit pores of various pore size to model activated carbon and a bundle of graphitic cylinders arranged hexagonally to model carbon nanotube. Carbon dioxide was modeled as a 3-center-Lennard-Jones (LJ) molecule with three fixed partial charges, while methane was modeled as a single LJ molecule. We have shown that the behavior of adsorption for both activated carbon and carbon nanotube is sensitive to pore width and the crossing of isotherms is observed because of the molecular packing, which favors commensurate packing for some pore sizes. Using the adsorption data of pure methane or carbon dioxide on activated carbon, we derived its pore size distribution (PSD), which was found to be in good agreement with the PSD obtained from the analysis of nitrogen adsorption data at 77 K. This derived PSD was used to describe isotherms at other temperatures as well as isotherms of mixture of carbon dioxide and methane in activated carbon and carbon nanotube at 273 and 300 K. Good agreement between the computed and experimental isotherm data was observed, thus justifying the use of a simple adsorption model.
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Microporous and mesoporous activated carbon produced from longan-seed biomass were impregnated with NaOH and used to capture CO2 from a simulated flue gas in a fixed-bed column. The process variables that were studied included types of activated carbon as characterized by the volume ratio of micropores and mesopores (Vmic/Vmes), adsorption temperature, NaOH loading, gas feed rate and the adsorbent amount. All five process variables affected the two important breakthrough parameters, namely the breakthrough time (tB) and CO2 adsorption capacity at breakthrough time (qB), with different trends and degrees. However, it was only the NaOH loading that showed a characteristic of an optimum loading that provided the maximum of the breakthrough parameters. It was found that an approximate 45% increase in the adsorbed amount of CO2 could be achieved with the activated carbon impregnated with around 1 weight % NaOH solution as compared to the case of the non-impregnated carbon. The response surface methodology (RSM) was applied to develop the correlations for both tB and qB and the maximum predicted qB of 33.58 mg/g was derived at the NaOH loading of 76.5 mg/g carbon, Vmic/Vmes of 2.83, adsorption temperature of 20°C, gas feed rate of 156 kg/m2-h and adsorbent amount of 51 kg/m2 of column cross-section area. The Klinkenberg's breakthrough model was able to describe the CO2 breakthrough curves reasonably well for all the tested conditions. The analysis of the two model parameters, the affinity constant (K) and the effective pore diffusivity (De), revealed that the optimum Vmic/Vmes that provided the maximum K value was around 2.90, corresponding to the activated carbon that contains 74% and 26% by volume of micropores and mesopores, respectively. The proper volume ratio of micropores and mesopores along with alkali addition into activated carbon can be effectively used for maximizing CO2 adsorption in a fixed-bed adsorption system.
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Dióxido de Carbono , Carbón Orgánico , Hidróxido de Sodio , Adsorción , TemperaturaRESUMEN
High-surface-area microporous-mesoporous carbons were produced from carbon gel by applying the three consecutive steps of air oxidation, thermal treatment, and activation (the OTA method) to the gel. The formation of mesopores occurs both inside and outside the nanoparticles which form the carbon gel, while micropores are predominantly created within the nanoparticles. The OTA method offered a greater increase in pore volume and BET surface area of the resulting activated carbon in comparison with conventional CO2 activation either under the same activation conditions or at the same degree of carbon burn-off. Under the best preparation conditions, the maximum values of micropore volume, mesopore volume, and BET surface area achievable using the OTA method were found to be 1.19 cm3 g-1, 1.81 cm3 g-1, and 2920 m2 g-1, respectively at a 72% carbon burn-off. The larger increase in porous properties of activated carbon gel prepared by the OTA method over those based on conventional activation stems from the effects of the oxidation and heat treatment steps of the OTA method that could produce a large number of reaction sites which lead to efficient pore formation during the following CO2 activation process.
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We have refined and improved the computational efficiency of the TriPOD technique, used to determine the accessible characteristics of porous solids with a known configuration of solid atoms. Instead of placing a probe molecule randomly, as described in the original version of the TriPOD method (Herrera et al., 2011), we implemented a scheme for dividing the porous solid into 3D-grids and computing the solid-fluid potential energies at these grid points. We illustrate the potential of this technique in determining the total pore volume, the surface area and the pore size distribution of various molecular models of porous carbons, ranging from simple pore models to a more complex simulated porous carbon model; the latter is constructed from a canonical Monte Carlo simulation of carbon microcrystallites of various sizes.
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The effect of steam gasification conditions on products properties was investigated in a bubbling fluidized bed reactor, using larch wood as the starting material. For bed material effect, calcined limestone and calcined waste concrete gave high content of H(2) and CO(2), while silica sand provided the high content of CO. At 650 degrees C, calcined limestone proved to be most effective for tar adsorption and showed high ability to adsorb CO(2) in bed. At 750 degrees C it could not capture CO(2) but still gave the highest cold gas efficiency (% LHV) of 79.61%. Steam gasification gave higher amount of gas product and higher H(2)/CO ratio than those obtained with N(2) pyrolysis. The combined use of calcined limestone and calcined waste concrete with equal proportion contributed relatively the same gas composition, gas yield and cold gas efficiency as those of calcined limestone, but showed less attrition, sintering, and agglomeration propensities similar to the use of calcined waste concrete alone.