Novel nanocomposite thin film in the efficient removal of antibiotics using visible light: Insights of photocatalytic reactions and stability of thin film in real water implications.

Novel clay (bentonite) supported Ag0 nanoparticles (NPs) doped TiO2 nanocomposite (Clay/TiO2/Ag0(NPs)) thin film was obtained by using template synthesis method. The nanocomposite material is decorated with cubical Ag0(NPs) and utilised successfully in the photocatalytic degradation of tetracycline (TC) and sulfamethazine (SMZ) from aqueous solutions utilizing visible light and UV-A radiations. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS) analyses were used to characterise the nanocomposite materials. Diffusion reflectance spectroscopy (DRS) was utilised to determine the bandgap energies of the materials and also to confirm that Ag0(NPs) was successfully doped with TiO2. The nanocomposite material showed highly efficient photocatalytic activity for the breaking down of TC/SMZ under visible light irradiation by the enhanced electron-hole separation and adsorption of antibiotics at the vicinity of the catalyst. The oxidative degradation of TC/SMZ were shown to be highly dependent on the pH, initial concentration of TC/SMZ, and various co-existing ions. Reusability test of Clay/Ag0(NPs)/TiO2 nanocomposite revealed that the activity did not decline with repeated use. Treatment of TC and SMZ in real water system further enhanced the application potential of the novel catalysts for the treatment of full-scale wastewater polluted with these antibiotics.

Novel cubical Ag(NP) decorated titanium dioxide supported bentonite thin film in the efficient removal of bisphenol A using visible light.

The persistent endocrine-disrupting chemical bisphenol A is posing serious health concerns; hence, it is known to be an emerging and potential water contaminant. The present investigation aims to synthesize novel cubical Ag(NP) decorated titanium dioxide-supported bentonite (Ag/TiO2@Clay) nanocomposite using a novel synthetic process. The nanocomposite materials were characterized by several analytical methods viz., transmission electron microscopy (TEM), X-ray diffraction (XRD) analyses, energy-dispersive X-ray spectroscopy (EDX), atomic force microscopy (AFM), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) and diffuse reflectance spectroscopy (DRS). Further, the photocatalytic removal of bisphenol A was conducted utilizing the thin film catalyst under the LED (light emitting diode; visible light) and UV-A (ultra violet-A) light sources. The parametric studies solution pH (6.0-12.0), pollutant concentrations (1.0-20.0 mg/L), and the interaction of several scavengers and co-existing ions are studied extensively to demonstrate the insights of the removal mechanism. The mineralization of bisphenol A and repeated use of the thin film catalyst showed the potential usage of photocatalysts in the devised large-scale operations. Similarly, the natural matrix treatment was performed to evaluate the suitability of the process for real implications.

Noble metal-doped TiO2 thin films in the efficient removal of Mordant Orange-1: insights of degradation process.

Nanocomposite Ag0(NPs)/TiO2 is synthesised in a facile template method enabling nanoparticles of reduced Ag evenly distributed within the titania network. The morphological studies of nanocomposites were extensively performed employing SEM/EDX (scanning electron microscopy/energy dispersive X-ray), TEM (transmission electron microscopy) and AFM (atomic force microscopy). Moreover, the bandgap energies of materials were obtained using the diffuse reflectance spectrometer (DRS). The newer insights in the photocatalytic elimination of Mordant Orange-1 (MO1) was obtained using the nanocomposite thin film for various parametric studies utilising the UV-A and LED illuminations. The kinetics of degradation of MO1 was performed, and the rate constant was favoured at lower concentrations of MO1. Moreover, the elimination efficiency of MO1 was favoured with a decrease in solution pH. The NPOC results inferred that a fairly good extent of MO1 was mineralised using a thin-film catalyst for both the UV-A and LED illuminations. The minimal effect of several co-ions demonstrated the applicability of thin films in the elimination of MO1, and the stability of the thin film has shown the potential applicability of thin-film catalysts. Further, the mechanism of photocatalytic degradation was demonstrated with the radical scavenger studies and ascertained the reaction pathways.