Remarkably favorable hydration of carbonyl substituents in dicationic bis(arene) ruthenium complexes.
J Am Chem Soc
; 125(5): 1188-9, 2003 Feb 05.
Article
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| MEDLINE
| ID: mdl-12553819
ABSTRACT
The addition of water and methanol to the carbonyl substituents in the dicationic bis(arene)ruthenium complexes [(p-cymene)Ru(C6H5CHO)][OTf]2 (1) and [(p-cymene)Ru(C6H5C(O)CH3)][OTf]2 (2) is remarkably favorable-the equilibrium constants for these reactions are 1 million times greater than those for uncomplexed benzaldehyde and acetophenone. The addition of methanol to the carbonyl group in the o-anisaldehyde complex, [(p-cymene)Ru(C6H4{OCH3}CHO)][OTf]2 (6), occurs with a high degree of kinetic selectivity (94% de).
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Banco de datos:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Año:
2003
Tipo del documento:
Article
País de afiliación:
Estados Unidos