Solid state multinuclear NMR study of sigma-acetylide complexes of platinum, trans-[ClPt(PnBu3)2-C=C-p-C6H4-C=C-Pt(PnBu3)2Cl] and trans-[-Pt(PnBu3)2-C=C-p-C6H4-C=C-]n.
Solid State Nucl Magn Reson
; 1(1): 13-6, 1992 Feb.
Article
en En
| MEDLINE
| ID: mdl-1365709
ABSTRACT
Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric sigma-acetylide complexes of platinum, trans-[ClPt(PnBu3)2-C identical to C-p-C6H4-C identical to C-Pt(PnBu3)2Cl] and trans-[-Pt(PnBu3)2-C identical to C-p-C6H4-C identical to C-]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.
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Banco de datos:
MEDLINE
Asunto principal:
Compuestos Organoplatinos
/
Polímeros
/
Acetileno
/
Espectroscopía de Resonancia Magnética
Idioma:
En
Revista:
Solid State Nucl Magn Reson
Asunto de la revista:
DIAGNOSTICO POR IMAGEM
/
MEDICINA NUCLEAR
Año:
1992
Tipo del documento:
Article
País de afiliación:
Reino Unido