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[1,2-Bis(diphenyl-phosphino)ethane]-chlorido(η-penta-methyl-cyclo-penta-dien-yl)iron(II) dichloro-methane solvate.
Ou, Ya-Ping; Feng, Dan; Yuan, Jing-Jing.
Afiliación
  • Ou YP; Key Laboratory of Pesticides and Chemical Biology of the Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online ; 66(Pt 8): m921, 2010 Jul 10.
Article en En | MEDLINE | ID: mdl-21588156
ABSTRACT
In the title compound, [Fe(C(10)H(15))Cl(C(26)H(24)P(2))]·CH(2)Cl(2), the Fe(II) atom is coordinated by two P atoms from a 1,2-bis-(diphenyl-phosphino)ethane ligand [Fe-P = 2.2130 (7) and 2.2231 (7) Å], a chloride anion [Fe-Cl = 2.3329 (7) Å] and a penta-methyl-cyclo-penta-dienyl (Cp*) ligand [Fe-centroid(Cp*) = 1.732 (3) Å] in a typical piano-stool geometry. In the crystal structure, the complex and solvent mol-ecules are paired via weak C-H⋯Cl inter-actions.

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Año: 2010 Tipo del documento: Article

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Año: 2010 Tipo del documento: Article