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Imaging the Predicted Isomerism of Oligo(aniline)s: A Scanning Tunneling Microscopy Study.
Thomas, James O; Andrade, Hugo D; Mills, Benjamin M; Fox, Neil A; Hoerber, Heinrich J K; Faul, Charl F J.
Afiliación
  • Thomas JO; Bristol Centre for Functional Nanomaterials, Centre for NSQI, University of Bristol, Tyndall Avenue, BS8 1FD, UK.
  • Andrade HD; H. H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, BS8 1TL, UK.
  • Mills BM; H. H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, BS8 1TL, UK.
  • Fox NA; School of Chemistry, University of Bristol, Cantock's Close, BS8 1TS, UK.
  • Hoerber HJ; H. H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, BS8 1TL, UK.
  • Faul CF; H. H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, BS8 1TL, UK.
Small ; 11(28): 3430-4, 2015 Jul.
Article en En | MEDLINE | ID: mdl-25786786
The self-assembly of two emeraldine base tetra(aniline) derivatives is investigated using scanning tunneling microscopy. A combination of the scanning tunneling microscopy data and calculations reveals the presence of predicted cis/trans isomerism in this oxidation state. This isomerism is shown to hinder self-assembly into ordered structures, and provides indications as to why the properties of these materials, and their parent polymer, polyaniline, remain unfulfilled.
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Texto completo: 1 Banco de datos: MEDLINE Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Small Asunto de la revista: ENGENHARIA BIOMEDICA Año: 2015 Tipo del documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Banco de datos: MEDLINE Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Small Asunto de la revista: ENGENHARIA BIOMEDICA Año: 2015 Tipo del documento: Article