Bithiophenesulfonamide Building Block for π-Conjugated Donor-Acceptor Semiconductors.
J Am Chem Soc
; 138(22): 6944-7, 2016 06 08.
Article
en En
| MEDLINE
| ID: mdl-27210233
ABSTRACT
We report here π-conjugated small molecules and polymers based on the new π-acceptor building block, bithiophenesulfonamide (BTSA). Molecular orbital computations and optical, electrochemical, and crystal structure analyses illuminate the architecture and electronic structure of the BTSA unit versus other acceptor building blocks. Field-effect transistors and photovoltaic cells demonstrate that BTSA is a promising unit for the construction of π-conjugated semiconducting materials.
Texto completo:
1
Banco de datos:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Año:
2016
Tipo del documento:
Article