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Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.
Xiao, Hongde; Wang, Gang; Krische, Michael J.
Afiliación
  • Xiao H; University of Texas at Austin, Department of Chemistry, 105 E 24th St. A5300, Austin, TX, 78712-1167, USA.
  • Wang G; University of Texas at Austin, Department of Chemistry, 105 E 24th St. A5300, Austin, TX, 78712-1167, USA.
  • Krische MJ; University of Texas at Austin, Department of Chemistry, 105 E 24th St. A5300, Austin, TX, 78712-1167, USA.
Angew Chem Int Ed Engl ; 55(52): 16119-16122, 2016 12 23.
Article en En | MEDLINE | ID: mdl-27910228
ABSTRACT
Transfer hydrogenative coupling of styrene with primary alcohols using the precatalyst HClRu(CO)(PCy3 )2 modified by AgOTf or HBF4 delivers branched or linear adducts from benzylic or aliphatic alcohols, respectively. Related 2-propanol mediated reductive couplings also are described.
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Texto completo: 1 Banco de datos: MEDLINE Asunto principal: Rutenio / Estireno / Alcoholes / Aldehídos Idioma: En Revista: Angew Chem Int Ed Engl Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
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Texto completo: 1 Banco de datos: MEDLINE Asunto principal: Rutenio / Estireno / Alcoholes / Aldehídos Idioma: En Revista: Angew Chem Int Ed Engl Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos