Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand.

Schnitzler, S; Cui, P; Spaniol, T P; Okuda, J

Schnitzler, S; Cui, P; Spaniol, T P; Okuda, J.

Afiliación

Schnitzler S; Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
Cui P; Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
Spaniol TP; Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
Okuda J; Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.

Dalton Trans ; 46(6): 1761-1765, 2017 Feb 14.

Article en En | MEDLINE | ID: mdl-28120981

RESUMEN

Molecular magnesium hydride with a terminal metal-hydrogen bond [Mg(iPr2TACN·AliBu3)H]2 supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(µ-H)]2, exhibiting a rare MgH-Al interaction.

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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article País de afiliación: Alemania

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