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In Situ Monitoring Potential-Dependent Electrochemical Process by Liquid NMR Spectroelectrochemical Determination: A Proof-of-Concept Study.
Cao, Shuo-Hui; Ni, Zu-Rong; Huang, Long; Sun, Hui-Jun; Tang, Biao; Lin, Liang-Jie; Huang, Yu-Qing; Zhou, Zhi-You; Sun, Shi-Gang; Chen, Zhong.
Afiliación
  • Cao SH; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Ni ZR; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Huang L; Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Sun HJ; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Tang B; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Lin LJ; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Huang YQ; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Zhou ZY; Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Sun SG; Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
  • Chen Z; Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University , Xiamen 361005, P. R. China.
Anal Chem ; 89(7): 3810-3813, 2017 04 04.
Article en En | MEDLINE | ID: mdl-28318236
We report the design and the performance of a two-chamber thin-layer electrochemical device for in situ potential-dependent liquid NMR measurement. Liquid NMR spectra, simultaneously recorded with cyclic voltammetry (CV), have been obtained to reveal molecular changes with potentials scanning. As a proof of concept, redox properties of 1,4-benzoquinone based systems have been investigated, and a π dimerization has been identified by combining both in situ and ex situ NMR analyses. This work provides a new approach for spectroelectrochemistry, which will contribute to developing electrochemical NMR (EC-NMR) as an important tool for the analysis of electrochemical process at a molecular level.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Anal Chem Año: 2017 Tipo del documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Anal Chem Año: 2017 Tipo del documento: Article