Graphene oxide-dye nanocomposites: effect of molecular structure on the quality of laser-induced graphene.

The nanocomposite coatings made using graphene oxide (GO) and six different organic dyes were used to produce the laser-induced graphene (LIG) coatings by means of near infrared picosecond laser irradiation. The coatings were investigated by means of contact angle measurement with three liquids (1-bromonaphtalene, glycerol and water), Raman spectroscopy, scanning electron microscopy, Fourier transform infrared (FTIR) spectroscopy and thermogravimetric analysis. It was found that the more hydrophilic is the precursor surface the more hydrophobic LIG surface is produced after the laser treatment. Contact angle values obtained on LIG produced from pure GO reached 143°. FTIR spectra have shown that the interaction between GO and dye molecules is realized through the nitrogen atoms. Raman spectra have shown that the best quality LIG coating is obtained using a GO-neutral red nanocomposite precursor. A correlation among contact angle, Raman spectra and topological indices of dye molecules was found, and will serve for the further investigation of the mechanism of LIG production and development of low-defect coatings.