Autoluminescent Metal-Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF.
J Am Chem Soc
; 140(43): 14144-14149, 2018 Oct 31.
Article
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| MEDLINE
| ID: mdl-30285430
ABSTRACT
A novel thorium(IV) metal-organic framework (MOF), Th(2,6-naphtalenedicarboxylate)2, has been synthesized via solvothermal reaction of thorium nitrate and 2,6-naphtalendicarboxilyc acid. This compound shows a new structural arrangement with an interesting topology and an excellent thermal resistance, as the framework is stable in air up to 450 °C. Most notably, this MOF, combining the radioactivity of its metal center and the scintillation property of the ligand, has been proven capable of spontaneous photon emission.
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MEDLINE
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En
Revista:
J Am Chem Soc
Año:
2018
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Article
País de afiliación:
Italia