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Controllable Phosphorylation of Thioesters: Selective Synthesis of Aryl and Benzyl Phosphoryl Compounds.
Xu, Kaiqiang; Liu, Long; Li, Zhaohui; Huang, Tianzeng; Xiang, Kang; Chen, Tieqiao.
Afiliación
  • Xu K; Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
  • Liu L; Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
  • Li Z; Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
  • Huang T; Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
  • Xiang K; Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
  • Chen T; Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
J Org Chem ; 85(22): 14653-14663, 2020 11 20.
Article en En | MEDLINE | ID: mdl-32924481
ABSTRACT
The controllable phosphorylations of thioesters were developed. When the reaction was catalyzed by a palladium catalyst, aryl or alkenyl phosphoryl compounds were generated through decarbonylative coupling, while the benzyl phosphoryl compounds were produced through deoxygenative coupling when the reaction was carried out in the presence of only a base.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2020 Tipo del documento: Article País de afiliación: China
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2020 Tipo del documento: Article País de afiliación: China