Laser-Accelerated Mass Transport in Oxygen Reduction Via a Graphene-Supported Silver-Iron Oxide Heterojunction.
J Phys Chem Lett
; 13(18): 4200-4206, 2022 May 12.
Article
en En
| MEDLINE
| ID: mdl-35511593
ABSTRACT
Mass-transport acceleration is essential toward enhanced electrocatalytic performance yet rarely recognized under irradiation, because light is usually reported to improve charge transfer. We studied laser-enhanced mass transport through the heterojunction between Ag and semiconductor Fe2O3 situated on graphene for oxygen reduction reaction. Because of the decreased mass-transport resistance by 59% under 405 nm laser irradiation, the current density can be enhanced by 180%, which is also supported by a theoretical calculation. This laser-enhanced mass transport was attributed to local photothermal heating and the near-field local enhancement. Easier desorption of OH- species occurring between the Fe and Ag centers under the laser accelerates the mass-transport centers.
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MEDLINE
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En
Revista:
J Phys Chem Lett
Año:
2022
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Article
País de afiliación:
Taiwán