Synthesis of pyrrole-based PSiP pincer ligands and their palladium, rhodium, and platinum complexes.
Dalton Trans
; 51(20): 7797-7803, 2022 May 24.
Article
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| MEDLINE
| ID: mdl-35543443
ABSTRACT
The synthesis and coordination chemistry of a new class of silyl pincer ligand featuring pyrrole-based linkers is reported. The steric and electronic properties of these bis(phosphinopyrrole)methylsilane ligands were interrogated using their palladium, rhodium, and platinum complexes. The pyrrole-based linker attenuates the donor ability of the ligand relative to its reported 1,2-phenylene congener while maintaining a similar steric profile. Additionally, the silyl donor connected to the N-pyrrolyl groups exhibits a weaker trans influence than the analogous ligand featuring 1,2-phenylene linkers.
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Banco de datos:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Asunto de la revista:
QUIMICA
Año:
2022
Tipo del documento:
Article
País de afiliación:
Estados Unidos