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Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes.
Chu, Zhenwei; Li, Jinhua; Hua, Yuhui; Luo, Ming; Chen, Dafa; Xia, Haiping.
Afiliación
  • Chu Z; Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China. chendf@sustech.edu.cn.
  • Li J; Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China. chendf@sustech.edu.cn.
  • Hua Y; Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China. chendf@sustech.edu.cn.
  • Luo M; Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China. chendf@sustech.edu.cn.
  • Chen D; Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China. chendf@sustech.edu.cn.
  • Xia H; Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China. chendf@sustech.edu.cn.
Chem Commun (Camb) ; 59(28): 4173-4176, 2023 Apr 04.
Article en En | MEDLINE | ID: mdl-36939834
ABSTRACT
Four diaza-osmapentalenes were prepared by two-step reactions, through the treatment of an alkyne-coordinated osmium complex with azo compounds, followed by the addition of AgSbF6/CO. Their aromaticity was confirmed by crystal parameters, NMR spectra and theoretical calculations. These complexes are the first diaza-metallapentalenes representing a new class of metallaaromatics.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article