Hetero-carbolong chemistry: experimental and theoretical studies of diaza-metallapentalenes.
Chem Commun (Camb)
; 59(28): 4173-4176, 2023 Apr 04.
Article
en En
| MEDLINE
| ID: mdl-36939834
ABSTRACT
Four diaza-osmapentalenes were prepared by two-step reactions, through the treatment of an alkyne-coordinated osmium complex with azo compounds, followed by the addition of AgSbF6/CO. Their aromaticity was confirmed by crystal parameters, NMR spectra and theoretical calculations. These complexes are the first diaza-metallapentalenes representing a new class of metallaaromatics.
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Banco de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2023
Tipo del documento:
Article